Skip to main content
SpringerLink
Log in

Phosphorylation of Pyrimidinophane in the Reversed Micellar Solutions of Cationic and Nonionogenic Surfactants

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Reactions of a macrocycle containing three pyrimidine fragments and N,N′-bis(2-methylthio-6-methylpyrimidin-4-yl)-hexamethylenediamine with p-nitrophenyl bis(chloromethyl)phosphinate in the micellar solutions of cetyltrimethylammonium bromide, polyethyleneglycol-600 laurate and their mixture in chloroform was investigated spectrophotometrically. Catalytic activity of micelles depends on their structure, concentration of surfactants, molar fraction of the latter in solution, and structure of the nucleophilic reagent.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Pileni, M.P., J. Phys. Chem., 1993, vol. 97, no.27, p. 6971.

    Article  Google Scholar 

  2. Studies in Physical and Theoretical Chemistry. 65. Structure and Reactivity in Reverse Micelles, Pileny, M.P., Ed., Amsterdam, 1989.

  3. Khmelnitskii, Yu.L., Levashow, A.V., Klyachko, N.L., and Martinek, K., Biotechnology, 1988, vol. 4, no.3, p. 292.

    CAS  Google Scholar 

  4. Chang, G.G., Huang, T.M., and Hung, H.C., Proc. Natl. Sci. Counc. Roc (B), 2000, vol. 24, no.3, p. 89.

    CAS  Google Scholar 

  5. Mwalupindi, A.G., Ndou, T.T., and Warner, I.M., Anal. Chem., 1992, vol. 64, no.17, p. 1840.

    Article  CAS  Google Scholar 

  6. Kabanov, A.V., Krutskaya, M.M., Eremin, S.A., Klyachko, N.L., and Levashov, A.V., Anal. Biochem., 1989, vol. 181, no.1, p. 145.

    Article  CAS  Google Scholar 

  7. McDonald, J.A. and Rennie, A.R., Langmuir., 1995, vol. 11, no.5, p. 1493.

    Article  CAS  Google Scholar 

  8. Zakharova, L.Ya., Valeeva, F.G., Zakharov, A.V., Ibragimova, A.R., Kudryavtseva, L.A., and Harlampidi, H.E., J. Colloid Interphace Sci., 2003, vol. 263, no.2, p. 597.

    CAS  Google Scholar 

  9. Zakharova, L.Ya., Valeeva, F.G., Ibragimova, A.P., Kudryavtseva, L.A., Valeev, H.H., Didenko, T.L., Kovalenko, V.I., and Konovalov, A.I., Izv. Akad. Nauk, Ser. Khim., 2002, no. 12, p. 2019.

  10. Mashimo, M., Sato, H., and Komasawa, I., J. Chem. Eng. Jpn, 1997, vol. 30, no.4, p. 712.

    CAS  Google Scholar 

  11. Yamada, Y., Kuboi, R., and Komasawa, I., J. Chem. Eng. Jpn, 1994, vol. 27, no.3, p. 404.

    Article  CAS  Google Scholar 

  12. Chiang, C.L., J. Colloid Interphase Sci., 2000, vol. 230, no.1, p. 60.

    CAS  Google Scholar 

  13. Rondinone, A.J., Samia, A.C.S., and Zhang, Z.J., J. Phys. Chem. (B), 1999, vol. 103, no.33, p. 6876.

    CAS  Google Scholar 

  14. Yamada, Y., Kuboi, R., and Komasawa, I., Biotechnol. Progr., 1993, vol. 9, no.5, p. 468.

    CAS  Google Scholar 

  15. Host-Guest Complex Chemistry (Macrocycles: Synthesis, Structures, Applications), Vogtle, F. and Weber, E., Eds., Berlin: Springer, 1985. Translated under the title Khimiya kompleksov “gost'-khozyain.” Sintez, struktura i promeneniya, Moscow: Mir, 1988.

    Google Scholar 

  16. Zhil'tsova, E.P., Timosheva, A.P., Shagidullina, R.A., Mustafina, A.R., Kudryavtseva, L.A., Kataev, V.E., Kazakova, E.Kh., Nikolaev, V.F., and Konovalov, A.I., Zh. Obshch. Khim., 2001, vol. 71, no.3, p. 419.

    Google Scholar 

  17. Tishkova, E.P., Kudryavtseva, L.A., Zakharova, L.Ya., and Fedorov, S.B., Izv. Akad. Nauk, Ser. Phys., 1996, vol. 60, no.4, p. 109

    CAS  Google Scholar 

  18. Bel'skii, V.E., Novikov, L.S., Kudryavtseva, L.A., and Ivanov, B.E., Zh. Obshch. Khim., 1978, vol. 48, no.7, p. 1512.

    Google Scholar 

  19. Zhil'tsova, E.P., Kudryavtseva, L.A., and Shagidullina, R.A., Izv. Akad. Nauk, Ser. Khim., 1999, no. 2, p. 275.

  20. Metody i dostizheniya v fisiko-organicheskoi khimii (Methods and Achievements in Physical Organic Chemistry), Femdler, E. and Fendler, J., Eds., Moscow: Mir, 1973.

    Google Scholar 

  21. Pantin, V.I., Levashov, A.I., Martinek, K., and Berezin, I.V., Dokl. Akad. Nauk SSSR, 1979, vol. 247, no.5, p. 1194.

    CAS  Google Scholar 

  22. Podmarkov, V.I. and Serdyuk, A.I., Kolloid. Zh., 1987, no. 6, p. 1111.

  23. Pilipenko, A.T., Saranskii, L.I., and Kulichenko, S.A., Zh. Anal. Khim., 1987, vol. 42, no.8, p. 1493.

    CAS  Google Scholar 

  24. Abramovich, S.Sh., Mingazova, R.A., and Fuks, G.I., Kolloid. Zh., 1976, vol. 38, no.2, p. 230.

    CAS  Google Scholar 

  25. Mikhailov, A.S., Giniyatullin, R.Kh., Semenov, V.E., Reznik, V.S., Nafikova, A.A., Latypov, Sh.K., Efremov, Yu.Ya., and Sharafutdinova, D.R., Izv. Ross. Akad. Nauk, Ser. Khim., 2003, no. 6, p. 1324.

  26. Gordon, A. and Ford, R., The Chemist's Companion, New York: Wiley, 1972. Translated under the title Sputnik khimika, Moscow: Mir, 1976.

    Google Scholar 

  27. Gur'yanova, E.N., Goldshtein, I.P., and Romm, I.P., Donorno-aktseptornaya svyaz' (Donor-acceptor Bond), Moscow: Khimiya, 1973.

    Google Scholar 

  28. Nigmatullin, R.Sh., Vyaselev, M.R., and Shatunov, V.S., Zavodskaya Laboratoriya, 1964, vol. 30, no.4, p. 500.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    E. P. Zhil'tsova, L. A. Kudryavtseva, G. A. Gainanova, A. P. Timosheva, A. S. Mikhailov, R. H. Giniyatullin, A. A. Nafikova, V. S. Reznik & A. I. Konovalov

Authors
  1. E. P. Zhil'tsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Kudryavtseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. A. Gainanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. P. Timosheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. S. Mikhailov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. R. H. Giniyatullin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. A. Nafikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. V. S. Reznik
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. A. I. Konovalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 11, 2005, pp. 1812–1817.

Original Russian Text Copyright © 2005 by Zhil'tsova, Kudryavtseva, Gainanova, Timosheva, Mikhailov, Giniyatullin, Nafikova, Reznik, Konovalov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zhil'tsova, E.P., Kudryavtseva, L.A., Gainanova, G.A. et al. Phosphorylation of Pyrimidinophane in the Reversed Micellar Solutions of Cationic and Nonionogenic Surfactants. Russ J Gen Chem 75, 1729–1734 (2005). https://doi.org/10.1007/s11176-005-0501-x

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11176-005-0501-x

Keywords

Search

Navigation