Skip to main content
SpringerLink
Log in

Reactions of Polyols with Boric Acid and Sodium Monoborate

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Complex formation was studied in the systems boric acid (sodium monoborate)-polyol (D-sorbitol, mannitol, dulcitol, xylitol, glycerol)-water, concentrational stability constants of the complexes and ionization constants of bis(polyol)boric acids were estimated. In the systems D-sorbitol, D-mannitol, dulcitol, glycerol-boric acid-water electric conductivity increases sharply to peak at the molar ratio polyol : boric acid = 2 : 1; in the case of dulcitol there appears yet another peak at the molar ratio polyol : boric acid = 1 : 1. In the systems D-sorbitol, D-mannitol, glycerol-sodium monoborate-water three complex anions: [BPolyol2]− in acidic, [BPolyol]−, and [B2Poyol]2- in neutral and basic regions of the system were revealed, their stability being dependent on the nature of the polyol and the overall concentration of the solution. In the system dulcitol-sodium monoborate-water only one complex anion [BDulc]− is formed, and in the system xylitol-sodium monoborate-water dimeric complex [BXyl]− is found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Shvarts, E.M., Vzaimodeisvi'ye bornoi kisloty so spirtami i oksikislotami (Reaction of Boric Acid with Alcohols and Hydroxy acids), Riga: Zinatne, 1990, p. 197.

    Google Scholar 

  2. Shvarts, E.M., Kompleksnye soedineniya bora s polyoksisoedineniyami (Complex Compounds of Boron with Polyhydroxy Compounds), Riga: Zinatne, 1968, p. 59.

    Google Scholar 

  3. Makkee, M., Kieboom, A., and Van Bekkum, A., Recl. Trav. Chim. Pays-Bas, 1985, vol. 104, no.9, p. 230.

    CAS  Google Scholar 

  4. Shvarts, E.M., Ignash, R.T., and Belousova, R.G., Zh. Obshch. Khim., 2000, vol. 70, no.1, p. 98.

    Google Scholar 

  5. Sciarra, J.J. and Elliot, D., J. Am. Pharm. Acc., 1960, vol. 49, no.2, p. 115.

    CAS  Google Scholar 

  6. Sciarra, J.J., Bovi, A., and Monte, J., J. Pharm Sci., 1962, vol. 51, no.3, p. 238.

    CAS  Google Scholar 

  7. Nazarenko, V.A. and Ermak, L.D., Zh. Neorg. Khim., 1967, vol. 12, no.8, p. 2051.

    Google Scholar 

  8. Nazarenko, V.A.and Ermak, L.D., Zh. Neorg. Khim., 1967, vol. 12, no.3, p. 643.

    CAS  Google Scholar 

  9. Putnin', A.Ja., Shvarts, E.M., and Ievin'sh, A.F., Zh. Neorg. Khim., 1973, vol. 18, no.6, p. 1504.

    Google Scholar 

  10. Shvarts, E.M., Krast's, Kh.B., Putninya, A.Ya., and Berge, B.Ja., Latv. Khim. Zh., 1998, no. 1, p. 39.

  11. Ignasa, R., Krast's, H., Kukurs, O., Svarca, J., and Zarina, Latv Pat. WO 03/000955, 2003.

  12. Gode, G.K., Sintesy boratov (Syntheses of Borates), Riga: Latv. State Univ., 1972, Part 2, p. 14.

    Google Scholar 

  13. Beck, M., Chemistry of Complex Equilibria, Budapest: Acad. Kiado, 1973.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Inorganic Chemistry, Riga Technical University, Riga, Latvia

    E. M. Shvarts, R. T. Ignash & R. G. Belousova

Authors
  1. E. M. Shvarts
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. T. Ignash
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. G. Belousova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 11, 2005, pp. 1768–1774.

Original Russian Text Copyright © 2005 by Shvarts, Ignash, Belousova.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shvarts, E.M., Ignash, R.T. & Belousova, R.G. Reactions of Polyols with Boric Acid and Sodium Monoborate. Russ J Gen Chem 75, 1687–1692 (2005). https://doi.org/10.1007/s11176-005-0492-7

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11176-005-0492-7

Keywords

Search

Navigation