Abstract
The aggregation in polyethylenimine-chloroform and cetyltrimethylammonium bromide-polyethylenimine-chloroform systems is studied by dielcometric titration. Inverse micelles of cetyltrimethylammonium bromide catalyze the phosphorylation of hydroxybenzylated polyethylenimines in chloroform. The dependence of parameters of the micelle-catalyzed reaction on the structure and concentration of polyethylenimine and on the reaction temperature is studied. The inverse micelles affect the complexation of polyethylenimines with 4-nitrophenol.
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Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 10, 2005, pp. 1681–1687.
Original Russian Text Copyright © 2005 by Zhil'tsova, Kudryavtseva, Gainanova, Timosheva, Lukashenko, Konovalov.
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Zhil'tsova, E.P., Kudryavtseva, L.A., Gainanova, G.A. et al. Inverse Micellar Catalysis of Phosphorylation of Hydroxybenzylated Polyethylenimines. Russ J Gen Chem 75, 1603–1609 (2005). https://doi.org/10.1007/s11176-005-0474-9
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DOI: https://doi.org/10.1007/s11176-005-0474-9