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Oxidation of Iron and Nickel with 3,5-Di-tert-butyl-1,2-benzoquinone in Coordinating Solvents

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Abstract

The final products of oxidation of iron and nickel with 3,5-di-tert-butyl-1,2-benzoquinone in DMSO were identified, and the formal-kinetics relationships of the process were elucidated. The apparent equilibrium constants, enthalpies, and entropies of adsorption of the reactants on the metal surfaces and the rate constants and activation energies of the reactions were determined.

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Authors and Affiliations

  1. Research Institute of Chemistry, Lobachevsky Nizhni Novgorod State University, Nizhni Novgorod, Russia

    S. V. Maslennikov, I. A. Aivaz'yan, I. V. Spirina & V. P. Maslennikov

  2. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhni Novgorod, Russia

    V. K. Cherkasov

Authors
  1. S. V. Maslennikov
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  2. I. A. Aivaz'yan
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  3. I. V. Spirina
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  4. V. K. Cherkasov
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  5. V. P. Maslennikov
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 10, 2005, pp. 1653–1655.

Original Russian Text Copyright © 2005 by S. Maslennikov, Aivaz'yan, Spirina, Cherkasov, V. Maslennikov.

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Maslennikov, S.V., Aivaz'yan, I.A., Spirina, I.V. et al. Oxidation of Iron and Nickel with 3,5-Di-tert-butyl-1,2-benzoquinone in Coordinating Solvents. Russ J Gen Chem 75, 1576–1578 (2005). https://doi.org/10.1007/s11176-005-0469-6

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  • DOI: https://doi.org/10.1007/s11176-005-0469-6

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