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Kinetics of Isothermal Pyrolysis of Iodomethanes in the Gas Phase

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Abstract

The limiting step of the isothermal pyrolysis of gaseous iodomethane (CH3I → 3/4CH4 + 1/2I2 + 1/(4n)C n ) and diiodomethane (CH2I2 → 1/2CH4 + I2 + 1/(2n)C n ) are the reactions 2CHI → C2 + 2HI and 2CI2 → C2 + 2I2, respectively. The rate constants of these reactions were determined.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    G. A. Skorobogatov, A. G. Rebrova & V. K. Khripun

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  1. G. A. Skorobogatov
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  2. A. G. Rebrova
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  3. V. K. Khripun
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 10, 2005, pp. 1600–1611.

Original Russian Text Copyright © 2005 by Skorobogatov, Rebrova, Khripun.

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Skorobogatov, G.A., Rebrova, A.G. & Khripun, V.K. Kinetics of Isothermal Pyrolysis of Iodomethanes in the Gas Phase. Russ J Gen Chem 75, 1524–1536 (2005). https://doi.org/10.1007/s11176-005-0462-0

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  • DOI: https://doi.org/10.1007/s11176-005-0462-0

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