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Nature of Bridging Bonds in Lithium and Potassium Acetate Dimers

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Abstract

The structures of lithium and potassium acetates were studied by the RHF/6-31G** quantum-chemical method. The metal-oxygen bonds in the dimers (CH3COOLi)2 and (CH3COOK)2 are electrostatic in nature. The bridging lithium bond is intermediate between hydrogen and ionic, and its peculiarity is determined by the deformation of molecular orbitals in the field of the lithium cation. The resulting data allow the variety of glassy smectic mesophases of lithium acetate.

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    I. A. Panteleev & S. G. Semenov

  2. Research Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russia

    D. N. Glebovskii

Authors
  1. I. A. Panteleev
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  2. S. G. Semenov
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  3. D. N. Glebovskii
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Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 9, 2005, pp. 1479–1484.

Original Russian Text Copyright © 2005 by Panteleev, Semenov, Glebovskii.

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Panteleev, I.A., Semenov, S.G. & Glebovskii, D.N. Nature of Bridging Bonds in Lithium and Potassium Acetate Dimers. Russ J Gen Chem 75, 1406–1410 (2005). https://doi.org/10.1007/s11176-005-0438-0

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  • DOI: https://doi.org/10.1007/s11176-005-0438-0

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