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Mixed Anionoarylation of Tetramethylene and Diethylene Glycol Diacrylates

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Abstract

The example of tetramethylene and diethylene glycol diacrylates was used to accomplish the first mixed anionoarylation. The reaction of diazonium salts with these unsaturated compounds gave chloroarylation adducts by one multiple bond: 1-acryloyloxy-4-(2-chloro-3-arylpropyonyloxy)butanes and 1-acryl-oyloxy-2-[2-(2-chloro-3-arylpropyonyloxy)ethoxy]ethanes. The latter were subjected to thiocyanatoarylation to obtain diadducts: 1-(2-chloro-3-arylpropyonyloxy)-4-(2-thiocyanato-3-arylpropyonyloxy)butanes and 1-(2-chloro-3-arylpropyonyloxy)-2-[2-(2-thiocyanato-3-arylpropyonyloxy)ethoxy]ethanes.

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REFERENCES

  1. Grishchuk, B.D., Baranovs’kii, V.S., Gorbovii, P.M., and Drozdova, E.L., Nauk. Zapiski Ternopil. Derzh. Ped. Univ., Ser. Khim., 2001, no. 5, p. 3.

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Authors and Affiliations

  1. Gnatyuk National Pedagogical University, Ternopol, Ukraine

    B. D. Grishchuk, V. S. Baranovskii & P. M. Gorbovoi

Authors
  1. B. D. Grishchuk
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  2. V. S. Baranovskii
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  3. P. M. Gorbovoi
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Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 4, 2005, pp. 650–653.

Original Russian Text Copyright © 2005 by Grishchuk, Baranovskii, Gorbovoi.

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Grishchuk, B.D., Baranovskii, V.S. & Gorbovoi, P.M. Mixed Anionoarylation of Tetramethylene and Diethylene Glycol Diacrylates. Russ J Gen Chem 75, 613–616 (2005). https://doi.org/10.1007/s11176-005-0281-3

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  • DOI: https://doi.org/10.1007/s11176-005-0281-3

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