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Diazo Reactions with Unsaturated Compounds: IX. ortho-, meta-, and para-Nitrophenylsulfonyl-1,3-butadienes in Reaction with 1-Aryl-3,3-dimethyl-1-triazenes

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Abstract

1-(m-Nitrophenylsulfonyl)- and 1-(p-nitrophenylsulfonyl)-1,3-butadienes in aqueous acetone in the presence of HCl and copper(I) or copper(II) chloride react with 1-aryl-3,3-dimethyl-1-triaenes to form 1-(m-nitrophenylsulfonyl)- and 1-(p-nitrophenylsulfonyl)-4-aryl-3-chloro-1-butenes, respectively. 1-(o-Nitro-phenylsulfonyl)-1,3-butadiene fails to react in similar conditions.

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Authors and Affiliations

  1. Khmel’nitskii National University, Cherkassy, Ukraine

    V. M. Naidan & V. V. Smalius

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  1. V. M. Naidan
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  2. V. V. Smalius
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 4, 2005, pp. 619–621.

Original Russian Text Copyright © 2005 by Naidan, Smalius.

For communication VIII, see [1].

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Naidan, V.M., Smalius, V.V. Diazo Reactions with Unsaturated Compounds: IX. ortho-, meta-, and para-Nitrophenylsulfonyl-1,3-butadienes in Reaction with 1-Aryl-3,3-dimethyl-1-triazenes. Russ J Gen Chem 75, 580–582 (2005). https://doi.org/10.1007/s11176-005-0275-1

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  • DOI: https://doi.org/10.1007/s11176-005-0275-1

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