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Gas-Phase Reaction of Anisole and Phenol with Tetrachlorogermane in the Presence of Hexachlorodisilane

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Abstract

Gas-phase reaction of anisole with tetrachlorogermane in the presence of hexachlorodisilane was studied. The major reaction products are chloro(phenoxy)silane, trichloro(phenoxy)germane, 1,1,3,3-tetrachloro-1,3-disila-2-oxaindane, and 1,1,3,3-tetrachloro-1,3-digerma-2-oxaindane. The same products are formed with phenol instead of anisole. A mechanism of the reactions of anisole with GeCl4 and Si2Cl6 is proposed, that takes account of the formation in the reaction zone of dichlorosilylenes and dichlorogermylenes.

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Authors and Affiliations

  1. State Research Institute of Chemistry and Technology of Organoelement Compounds State Research Center, Moscow, Russia

    E. A. Chernyshev, V. G. Bykovchenko, N. G. Komalenko, G. N. Yakovleva & M. M. Simakina

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  1. E. A. Chernyshev
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  2. V. G. Bykovchenko
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  3. N. G. Komalenko
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  4. G. N. Yakovleva
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  5. M. M. Simakina
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 4, 2005, pp. 606–609.

Original Russian Text Copyright © 2005 by Chernyshev, Bykovchenko, Komalenko, Yakovleva, Simakina.

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Chernyshev, E.A., Bykovchenko, V.G., Komalenko, N.G. et al. Gas-Phase Reaction of Anisole and Phenol with Tetrachlorogermane in the Presence of Hexachlorodisilane. Russ J Gen Chem 75, 567–570 (2005). https://doi.org/10.1007/s11176-005-0272-4

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  • DOI: https://doi.org/10.1007/s11176-005-0272-4

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