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Synthesis and Study of Copper(II) Complexes with Aspartic Acid, Serine, and Valine

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Abstract

Binary and ternary copper(II) complexes with aspartic acid (H2Asp), serine (HSer), and valine (HVal) were prepared by electrochemical and chemical procedures. The purity of the compounds was confirmed by elemental and thermogravimetric analyses. According to the IR spectra, all the complexes contain a five-membered chelate ring in which the Cu(II) atom is bonded with the oxygen atom of the carboxy group and nitrogen atom of the amino group. This is also confirmed by the ESR spectra.

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REFERENCES

  1. Inorganic Biochemistry, Eichhorn G.L., Ed., Amsterdam: Elsevier, 1975.

    Google Scholar 

  2. Yatsimirskii, K.B., Problemy bioneorganicheskoi khimii (Problems of Bioinorganic Chemistry), Moscow: Znanie, 1976.

    Google Scholar 

  3. Hinojosa, M., Ortiz, R., Perello, L., and Borras, J., J. Inorg. Biochem., 1987, vol. 29, no.1, p. 119.

    Article  PubMed  Google Scholar 

  4. Weinstein, J. and Bielski, B.M., J. Am. Chem. Soc., 1980, vol. 102, no.20, p. 4916.

    Article  CAS  Google Scholar 

  5. Sanz, A.M.T., Rodriguez, P.J.C., and Garcia, M.F.J., Collect. Czech. Chem. Commun., 1992, vol. 57, no.7, p. 1405.

    Article  Google Scholar 

  6. Vasil’ev, V.P., Zaitseva, G.A., and Garfutdinova, L.V., Zh. Fiz. Khim., 1995, vol. 69, no.3, p. 506.

    CAS  Google Scholar 

  7. Yamauchi, O. and Odani, A., Inorg. Chim. Acta, 1985, vol. 100, no.1, p. 165.

    Article  CAS  Google Scholar 

  8. Kryukova, N.P., Bolotin, S.N., and Panyushkin, V.T., Izv. Ross. Akad. Nauk, Ser. Khim., 2003, no. 5, p. 1060.

  9. Gergely, A., Sovago, I., Nagypal, I., and Kiraly, R., Inorg. Chim. Acta, 1972, vol. 6, no.3, p. 435.

    Article  CAS  Google Scholar 

  10. Shoukry, M.M., Khairy, E.M., and Khalil, R.G., Transit. Met. Chem., 1997, vol. 22, no.5, p. 465.

    Article  CAS  Google Scholar 

  11. Esina, N.A., Molodkin, A.K., and Tarakanova, E.V., Zh. Neorg. Khim., 1996, vol. 41, no.11, p. 1874.

    CAS  Google Scholar 

  12. Cakir, S., Bicer, E., and Eleman, A., Transit. Met. Chem., 2001, vol. 26, no.1, p. 89.

    Article  CAS  Google Scholar 

  13. Frolov, V.Yu., Zelenov, V.I., and Panyushkin, V.T., Zh. Obshch. Khim., 1996, vol. 66, no.7, p. 1221.

    CAS  Google Scholar 

  14. Frolov, V.Yu., Cand. Sci. (Chem.) Dissertation, Krasnodar, 2001.

  15. Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York: Wiley, 1986.

    Google Scholar 

  16. Nakamura, K.J., Bull. Chem. Soc. Jpn., 1959, vol. 80, no.1, p. 113.

    CAS  Google Scholar 

  17. Shevchenko, L.L., Usp. Khim., 1963, vol. 32, no.4, p. 457.

    CAS  Google Scholar 

  18. Larin, G.M., Koord. Khim., 1994, vol. 20, no.12, p. 883.

    CAS  Google Scholar 

  19. Larin, G.M., Koord. Khim., 1999, vol. 25, no.11, p. 804.

    Google Scholar 

  20. Zuilhof, H., Bruin, T.J.M., Marcelis, A.T.M., and Sudholter, E.J.R., Phys. Chem. Chem. Phys., 1999, vol. 1, no.18, p. 4157.

    Google Scholar 

  21. Bogdashev, N.N., Garnovskii, A.D., Osipov, O.A., Grigor’ev, V.P., and Gontmakher, N.M., Zh. Obshch. Khim., 1976, vol. 46, no.3, p. 675.

    CAS  Google Scholar 

  22. Frolov, V. Yu., Zelenov, V.I., and Panyushkin, V.T., RF Patent 2 191 190, 2001, BIPM, 2002, no. 29.

  23. Schwarzenbach, G. und Flaschka, H., Die Komplexo-metrische Titration, Stuttgart: Ferdinand Enke, 1965.

    Google Scholar 

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Authors and Affiliations

  1. Kuban State University, Krasnodar, Russia

    N. P. Kryukova, V. Yu. Frolov, F. A. Kolokolov, S. N. Bolotin & V. T. Panyushkin

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  1. N. P. Kryukova
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  2. V. Yu. Frolov
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  3. F. A. Kolokolov
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  4. S. N. Bolotin
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  5. V. T. Panyushkin
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 4, 2005, pp. 541–544.

Original Russian Text Copyright © 2005 by Kryukova, Frolov, Kolokolov, Bolotin, Panyushkin.

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Kryukova, N.P., Frolov, V.Y., Kolokolov, F.A. et al. Synthesis and Study of Copper(II) Complexes with Aspartic Acid, Serine, and Valine. Russ J Gen Chem 75, 503–506 (2005). https://doi.org/10.1007/s11176-005-0261-7

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  • DOI: https://doi.org/10.1007/s11176-005-0261-7

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