Abstract
Oxidation of magnesium and thallium with bis(η5-cyclopentadienyltricarbonylmolybdenum) in dimethyl sulfoxide and of indium with octacarbonyldicobalt in tetrahydrofuran was studied. The formal-kinetics relationships of the processes were revealed, and the intermediate and final products were identified. The apparent equilibrium constants, enthalpies and entropies of adsorption of reactants on the metal surface, and rate constants and activation energies of the reactions were determined. The reaction scheme was suggested.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Von Haupt, H.J. and Neuman, F., Z. Anorg. Allg. Chem., 1972, vol. 394, nos.1–2, p. 67.
Bochkarev, L.N., Grachev, O.V., and Zhil’tsov, S.F., Metalloorg. Khim., 1993, vol. 6, no.2, p. 249.
Englich, U., Ruhlandt-Senge, K., and Uhlig, F.H., J. Organomet. Chem., 2000, vol. 597, no.2, p. 217.
Nesmeyanov, A.N., Makarova, L.G., and Vinogradova, V.N., Izv. Akad. Nauk SSSR, Ser. Khim., 1971, no. 9, p. 1984.
Baird, M.C., Chem. Rev., 1988, vol. 88, no.7, p. 1217.
Behrens, H., Ellermann, J., Merbach, P., and Weps, P., Z. Naturforsch. B, 1974, vol. 29, nos.7–8, p. 469.
Landrum, J.T. and Hoff, C.D., J. Organomet. Chem., 1985, vol. 282, no.2, p. 215.
Maslennikov, S.V., Spirina, I.V., Piskunov, A.V., and Maslennikov, V.P., Zh. Obshch. Khim., 2001, vol. 71, no.11, p. 1837.
Gutmann, V., Coordination Chemistry in Non-Aqueous Solutions, Wien: Springer, 1968.
McVicker, G.B. and Matyas, R.S., J. Chem. Soc., Chem. Commun., 1972, no. 17, p. 972.
Patmore, D.J. and Graham, W.A.G., Inorg. Chem., 1966, vol. 5, no.5, p. 1586.
Bremer, H. and Wendlandt, K.-P., Heterogene Katalyse: eine Einfuhrung, Berlin: Akademie, 1978.
Benson, S.W., The Foundations of Chemical Kinetics, New York: McGraw-Hill, 1960.
Walborsky, H.M. and Aronoff, M.S., J. Organomet. Chem., 1973, vol. 51, no.1, p. 33.
Maslennikov, S.V. and Spirina, I.V., Zh. Obshch. Khim., 1998, vol. 68, no.2, p. 300.
Gordon, A.J. and Ford, R.A., The Chemist’s Companion. A Handbook of Practical Data, Techniques, and References, New York: Wiley, 1972.
Charlot, G., Les methods de la chimie analytique. Analyse quantitative minerale, Paris: Masson, 1961, 4th ed.
Busev, A.I., Analiticheskaya khimiya molibdena (Analytical Chemistry of Molybdenum), Moscow: Akad. Nauk SSSR, 1962.
Spirina, I.V., Kholodalova, A.V., Selyakov, A.A., Alferov, V.A., and Maslennikov, V.P., Zh. Obshch. Khim., 1990, vol. 60, no.8, p. 1860.
Birdwhistell, R., Hackett, P., and Manning, A.R., J. Organomet. Chem., 1978, vol. 157, no.2, p. 239.
Hayter, R.G., Inorg. Chem., 1963, vol. 2, no.5, p. 1031.
Zhukov, S.A., Lavrent’ev, I.P., and Nifontova, T.A., Kinet. Catal. Lett., 1977, vol. 7, no.4, p. 405.
Author information
Authors and Affiliations
Additional information
__________
Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 4, 2005, pp. 529
Original Russian Text Copyright © 2005 by Maslennikov, Malysheva, Spirina, Artemov.
Rights and permissions
About this article
Cite this article
Maslennikov, S.V., Malysheva, E.V., Spirina, I.V. et al. Oxidation of Magnesium, Indium, and Thallium with Molybdenum and Cobalt Binuclear Carbonyl Complexes in Polar Solvents. Russ J Gen Chem 75, 491–495 (2005). https://doi.org/10.1007/s11176-005-0259-1
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11176-005-0259-1