Abstract
The possibility of isolation of crystalline supramolecular complexes of 18-crown-6 with glycine, L-alanine, L-valine, L-leucine, L-phenylalanine, L-proline, L-hystidine, and L-threonine from aqueous solutions was studied. Comparative analysis of thermal decomposition of the complexes and their individual components and mechanical mixture was studied by means of thermogravimetry, differential thermal analysis, and differential scanning calorimetry. Crystaline complexes of 18-crown-6 with glycine, L-alanine, and L-hystidine were isolated and shown to be stable up to 140°C, which was additionally confirmed by IR spectroscopy.
Similar content being viewed by others
REFERENCES
Hiraoka, M., Crown Compounds. Their Characteristics and Applications, Tokyo: Kodansha, 1982.
Kulikov, O.V. and Terekhova, I.V., Koord. Khim., 1997, vol. 23, no.12, p. 946.
Kulikov, O.V. and Terekhova, I.V., Koord. Khim., 1998, vol. 24, no.5, p. 395.
Lipkowski, J., Kulikov, O.V., and Zielenkiewicz, W., Supramol. Chem., 1992, vol. 1, no.1, p. 73.
Kulikov, O.V. and Kornilova, N.Yu., Zh. Fiz. Khim., 1996, vol. 70, no.12, p. 2119.
Ganin, E.V., Zakolodyazhnaya, O.V., and Makarov, V.F., Available from VINITI, 1987, Moscow, no. 3770-B87.
Rodante, F., Thermochim. Acta, 1992, vol. 200, no.1, p. 47.
Yigov, I., Yigov, F., and Banthin, A.K., Polym. Bull., 1981, vol. 4, p. 323.
Severini, F., Gallo, R., and Marullo, R., J. Therm. Anal., 1982, vol. 25, no.2, p. 515.
Tsivadze, O.Yu., Varnek, A.A., and Hutorskii, V.E., Koordinatsionnie soedineniya metallov s kraun-ligandami (Coordination Compounds of Metals with Crown Ligands), Moscow: Nauka, 1991.
Roberts, G.M., Lee, O., Calienni, J., and Diem, M., J. Am. Chem. Soc., 1988, vol. 110, no.6, p. 1749.
Bellamy, L.J., The Infra-red Spectra of Complex Molecules, London: Methuen, 1958.
Tsuboi, M., Takenishi, T., and Nakamura, A., Spectrochim. Acta, 1963, vol. 19, no.2, p. 203.
Zima, V., Benes, L., and Melanova, K., Solid State Ionics, 1998, vol. 106, p. 285.
Kulikov, O.V., Zielenkiewicz, W., and Utzig, E., Thermochim. Acta, 1994, vol. 237, no.2, p. 333.
Author information
Authors and Affiliations
Additional information
Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 8, 2004, pp. 1313–1317.
Original Russian Text Copyright © 2004 by Terekhova, Kulikov, Barannikov.
Rights and permissions
About this article
Cite this article
Terekhova, I.V., Kulikov, O.V. & Barannikov, V.P. Thermal dissociation of supramolecular complexes on the basis of 18-crown-6 and amino acids. Russ J Gen Chem 74, 1213–1217 (2004). https://doi.org/10.1007/s11176-005-0141-1
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11176-005-0141-1