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Thermodynamic parameters of intermolecular interaction in strongly associated solvents and their mixtures with dimethylformamide

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Abstract

The specific and nonspecific constituents of the total energy of intermolecular interasction in ethylene glycol, diethylene glycol, and formamide were determined for the range 288.15–323.15 K using a simulation approach. Diethylene glycol, like formamide and ethylene glycol, forms networks of hydrogen bonds. In ethylene glycol and formamide, the hydrogen bonds make a predominant contribution to the total interaction energy. The specific and nonspecific contributions in mixtures of the above solvents with dimethyl-formamide were calculated, and the results were discussed in combination with the data for aqueous dimethyl-formamide solutions.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Engineering, Ivanovo, Russia

    A. M. Zaichikov & M. A. Krest’yaninov

  2. Institute of Chemistry of Solutions, Russian Academy of Sciences, Ivanovo, Russia

    A. M. Zaichikov & M. A. Krest’yaninov

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  1. A. M. Zaichikov
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  2. M. A. Krest’yaninov
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Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 11, 2004, pp. 1789–1796.

Original Russian Text Copyright © 2004 by Zaichikov, Krest’yaninov

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Zaichikov, A.M., Krest’yaninov, M.A. Thermodynamic parameters of intermolecular interaction in strongly associated solvents and their mixtures with dimethylformamide. Russ J Gen Chem 74, 1665–1672 (2004). https://doi.org/10.1007/s11176-005-0081-9

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  • DOI: https://doi.org/10.1007/s11176-005-0081-9

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