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Synthesis of alkoxysilanes as starting substances for preparation of new materials by the sol-gel procedure. Silanes with urea functional group

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Abstract

New bis(triethoxysilanes) containing a urea functional group >NC(O)N< and having the composition (C2H5O)3Si(CH2)3NHC(O)NRR′ [R = R′ = n-C3H7; R = H, R′ = (CH2)3Si(CH3)(OC2H5)2] and [(C2H5O)3Si(CH2)3NHC(O)NH]2(CnAm)x (A = H, x = 2, 4, 12, n = 1, m = 2; A = H, CH3, x = 1, n = 6, m = 4; A = H, x = 1, n = 10, m = 6) were prepared in high yields and with satisfactory purity by reactions of primary amines (or diamines) with 3-(triethoxysilyl)propyl isocyanate.

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Authors and Affiliations

  1. Institute of Chemistry of Surface, National Academy of Sciences of Ukraine, Kiev, Ukraine

    I. V. Mel’nik, O. V. Lyashenko, Yu. L. Zub, A. A. Chuiko, D. Cauzzi & G. Predieri

  2. Department of General, Inorganic, Analytical, and Physical Chemistry, University of Parma, Parma, Italy

    I. V. Mel’nik, O. V. Lyashenko, Yu. L. Zub, A. A. Chuiko, D. Cauzzi & G. Predieri

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  1. I. V. Mel’nik
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  2. O. V. Lyashenko
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  3. Yu. L. Zub
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  4. A. A. Chuiko
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  5. D. Cauzzi
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  6. G. Predieri
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Additional information

Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 11, 2004, pp. 1782–1788.

Original Russian Text Copyright © 2004 by Mel’nik, Lyashenko, Zub, Chuiko, Cauzzi, Predieri.

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Mel’nik, I.V., Lyashenko, O.V., Zub, Y.L. et al. Synthesis of alkoxysilanes as starting substances for preparation of new materials by the sol-gel procedure. Silanes with urea functional group. Russ J Gen Chem 74, 1658–1664 (2004). https://doi.org/10.1007/s11176-005-0080-x

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  • DOI: https://doi.org/10.1007/s11176-005-0080-x

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