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Forms of iron occurrence in a series of binary tellurides FexTi1−x Te1.45

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Abstract

Nonstoichiometric tellurides FexTi1−x Te1.45 synthesized at 850°C were studied by X-ray phase and X-ray fluorescence analysis and by 57Fe Mössbauer spectroscopy. The mutual iron-titanium substitution is limited in this series. The system contains four individual phases in which iron is in three different states: Fe2+ in an asymmetric environment, Fe2+ in a symmetric environment, and Fe0. The distribution of various iron states in the system depends not only on the Fe : Ti ratio, but also on the structure of phases.

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REFERENCES

  1. Wells, A.F., Structural Inorganic Chemistry, Oxford: Oxford Univ. Press, 1983.

    Google Scholar 

  2. Pankratova, O.Yu., Grigor’eva, L.I., Zvinchuk, R.A., and Suvorov, A.V., Zh. Neorg. Khim., 1993, vol. 38, no.3, p. 410.

    Google Scholar 

  3. Vladimirova, V.A., Zvinchuk, R.A., Morozova, M.P., and Pankratova, O.Yu., Zh. Fiz. Khim., 1982, vol. 56, no.3, p. 565.

    Google Scholar 

  4. Irkaev, S.M., Kuz’min, R.N., and Opalenko, A.A., Yadernyi gamma-resonans (apparatura i metodika) (Mössbauer Spectroscopy (Instrumentation and Technique)), Moscow: Mosk. Gos. Univ., 1970.

    Google Scholar 

  5. Chemical Applications of Mossbauer Spectroscopy, Goldanskii, V.I. and Herber, R.H., Eds., New York: Academic, 1968. Translated under the title Khimicheskoe primenenie messbauerovskoi spektroskopii, Moscow: Mir, 1970, p. 500.

    Google Scholar 

  6. Ok, H.N. and Lee, S.W., J. Phys. Rev., 1973, vol. 8, no.9, p. 4267.

    Google Scholar 

  7. Bragg, LU. and Claringbule, G.F., Crustal Structures of Minerals, London: Bell, 1965.

    Google Scholar 

  8. Tsuji, T., Howe, A.T., and Greenwood, N.N., J. Solid State Chem., 1976, vol. 17, p. 157.

    Google Scholar 

  9. Blachnik, R., J. Less-Common Met., 1987, vol. 134, p. 169.

    Google Scholar 

  10. Stepanova, Yu.S., Grigor’eva, L.I., Pankratova, O.Yu., and Zvinchuk, R.A., Vestn. Sankt-Peterb. Gos. Univ., Ser. 4: Fiz., Khim., 2000, issue 2, no. 12, p. 114.

    Google Scholar 

  11. Reddy, K.V. and Chetty, S.C., Phys. Status Solidi (A), 1975, vol. 32, no.2. p. 585.

    Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State University, St. Petersburg, Russia

    O. Yu. Pankratova, A. V. Zabolotnaya, V. V. Panchuk, V. G. Semenov, R. A. Zvinchuk & A. V. Suvorov

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  1. O. Yu. Pankratova
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  2. A. V. Zabolotnaya
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  3. V. V. Panchuk
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  4. V. G. Semenov
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  5. R. A. Zvinchuk
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  6. A. V. Suvorov
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Additional information

Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 11, 2004, pp. 1761–1764.

Original Russian Text Copyright © 2004 by Pankratova, Zabolotnaya, Panchuk, Semenov, Zvinchuk, Suvorov.

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Pankratova, O.Y., Zabolotnaya, A.V., Panchuk, V.V. et al. Forms of iron occurrence in a series of binary tellurides FexTi1−x Te1.45 . Russ J Gen Chem 74, 1637–1640 (2004). https://doi.org/10.1007/s11176-005-0076-6

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  • DOI: https://doi.org/10.1007/s11176-005-0076-6

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