Liquid-phase oxidation of tert-butyldimethylsilane

Abstract

Kinetics and mechanism of liquid-phase oxidation of tert-butyldimethylsilane t-BuMe2SiH with molecular oxygen in the temperature range 297–350K were studied. Reaction orders in silane, initiator, and oxygen were evaluated. The major product of the oxidation of t-BuMe2SiH is tert-butyldimethylsilyl hydroperoxide t-BuMe2SiOOH. It was shown for the first time that the major reaction product is a silyl hydroperoxide. A kinetic scheme of the oxidation of t-BuMe2SiH is offered and discussed.

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Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 10, 2004, pp. 1625–1630.

Original Russian Text Copyright © 2004 by Lutsik-Maksim, Timokhin, Zaborovskii, Pristanskii, Turovskii, Chatgilialoglu.

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Lutsik-Maksim, D.S., Timokhin, V.I., Zaborovskii, A.B. et al. Liquid-phase oxidation of tert-butyldimethylsilane. Russ J Gen Chem 74, 1508–1512 (2004). https://doi.org/10.1007/s11176-005-0045-0

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Keywords

  • Oxidation
  • Oxygen
  • Silane
  • Hydroperoxide
  • Molecular Oxygen