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Thin-Layer Electrolytic Molybdenum Oxydisulfides for Cathodes of Lithium Batteries

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Abstract

Electrolytic molybdenum oxydisulfides are synthesized out of aqueous molybdate solutions containing sulfur in the presence of ions of Ni2+ with the aim of applying them as materials for ballastless cathodes of thin-layer lithium batteries. The physicochemical and structural properties of the synthesized compounds are studied profilometrically and by methods of thermal and x-ray diffraction analyses, absorption IR spectroscopy, and atomic force microscopy. Specific discharge characteristics, the chemical diffusion coefficient of lithium ions, the interaction parameter of intercalated ions, and the repulsion energy of intercalated ions in the process of intercalation and deintercalation of lithium ions in the synthesized materials are determined.

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Authors and Affiliations

  1. Ener 1, Ft. Lauderdale, FL, 33309, USA

    E. M. Shembel'

  2. Ukrainian State University of Chemical Technology, pr. Gagarina 8, Dnepropetrovsk, 49005, Ukraine

    E. M. Shembel', R. D. Apostolova & I. V. Kirsanova

  3. National Metallurgical Academy of Ukraine, Dnepropetrovsk, Ukraine

    V. P. Tysyachnyi

Authors
  1. E. M. Shembel'
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  2. R. D. Apostolova
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  3. V. P. Tysyachnyi
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  4. I. V. Kirsanova
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Correspondence to E. M. Shembel'.

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__________

Translated from Elektrokhimiya, Vol. 41, No. 12, 2005, pp. 1465–1475.

Original Russian Text Copyright © 2005 by Shembel', Apostolova, Tysyachnyi, Kirsanova.

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Shembel', E.M., Apostolova, R.D., Tysyachnyi, V.P. et al. Thin-Layer Electrolytic Molybdenum Oxydisulfides for Cathodes of Lithium Batteries. Russ J Electrochem 41, 1305–1315 (2005). https://doi.org/10.1007/s11175-005-0219-4

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  • DOI: https://doi.org/10.1007/s11175-005-0219-4

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