Skip to main content
SpringerLink
Log in

Application of a Zeolite-Poly(vinyl chloride) Electrode to Potentiometric Studies of Alkali Metal Ions

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Potentiometric electrodes based on the incorporation of zeolite particles into poly(vinyl chloride) (PVC) membranes are described. The electrode characteristics are evaluated regarding the response towards alkali ions. PVC membranes plasticized with dibutyl phthalate and without lipophilic additives (co-exchanger) are used throughout this study. The electrode exhibits a Nernstian response over the alkali metal cation concentration range of 1.0 × 10−4 to 1.0 × 10−1 M with a slope of 57.0 ± 0.9 mV per decade of concentration with a working pH range 3.0–9.0 and a fast response time of ≤15 s. The selectivity coefficients for cesium ion as test species with respect to alkaline earth, ammonium, and some heavy metal ions are determined. The proposed zeolite-PVC electrode is applied to the determination of ionic surfactant.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Ohki, A., Lu, J.P., and Bartsch, R.A., Anal. Chem., 1994, vol. 66, p. 651.

    CAS  Google Scholar 

  2. Ohki, A., Lu, J.P., and Bartsch, R.A., Anal. Chem., 1994, vol. 66, p. 4432.

    Google Scholar 

  3. Daunert, S. and Bachas, L.G., Anal. Chem., 1990, vol. 62, p. 1428.

    CAS  Google Scholar 

  4. Hutchins, R.S., Molina, P., Alajarin, M., Vidal, A., and Bachas, L.G., Anal. Chem., 1994, vol. 66, p. 3188.

    Article  CAS  Google Scholar 

  5. Jain, A.K., Gupta, V.K., Singh, L.P., and Khurana, U., Analyst, 1997, vol. 122, p. 583.

    Article  CAS  Google Scholar 

  6. Li, Z.Q., Wu, Z.Y., Yuan, R., Ying, M., and Shen, G.L., Yu. R.Q., Electrochim. Acta, 1999, vol. 44, p. 2543.

    CAS  Google Scholar 

  7. Rouhollahi, A. and Shamsipur, M., Anal. Chem., 1999, vol. 71, p. 1350.

    Article  CAS  Google Scholar 

  8. Badr, I.H.A., Diaz, M., Hawthorne, M.F., and Bachas, L.G., Anal. Chem., 1999, vol. 71, p. 1371.

    Article  CAS  Google Scholar 

  9. Rolison, D.R., Chem. Rev., 1990, vol. 90, p. 867.

    Article  CAS  Google Scholar 

  10. Walcarius, A., Electroanalysis, 1996, vol. 8, p. 971.

    Article  CAS  Google Scholar 

  11. Walcarius, A., Anal. Chim. Acta, 1999, vol. 384, p. 1.

    Article  CAS  Google Scholar 

  12. Wang, J. and Walcarius, A., J. Electroanal. Chem., 1996, vol. 407, p. 183.

    Article  CAS  Google Scholar 

  13. Liu, B., Hu, R., and Deng, J., Anal. Chem., 1997, vol. 69, p. 2343.

    CAS  Google Scholar 

  14. Marshall, C.E., J. Phys. Chem., 1939, vol. 43, p. 1155.

    Article  CAS  Google Scholar 

  15. Barrer, R.M. and James, S.D., J. Phys. Chem., 1960, vol. 64, pp. 417, 421.

    CAS  Google Scholar 

  16. Arvand-Barmchi, M., Mousavi, M.F., Zanjanchi, M.A., and Shamsipur, M., Microchemical, 2003, vol. 74, p. 149.

    CAS  Google Scholar 

  17. Mousavi, M.F., Arvand-Barmchi, M., and Zanjanchi, M.A., Electroanalysis, 2001, vol. 13, p. 1125.

    Article  CAS  Google Scholar 

  18. Johansson, G., Risinger, L., and Falth, L., Hung. Sci. Instr., 1980, p. 1125.

  19. Johansson, G., Risinger, L., and Falth, L., Anal. Chim. Acta, 1980, vol. 119, p. 25.

    Article  CAS  Google Scholar 

  20. Evmiridis, N.P., Demertzis, M.A., and Vlessidis, A.G., Fresenius J. Anal. Chem., 1991, vol. 340, p. 145.

    Article  CAS  Google Scholar 

  21. Matysik, S., Matusik, F.M., Mattusch, J., and Einicke, W.D., Electroanalysis, 1998, vol. 10, p. 98.

    Article  CAS  Google Scholar 

  22. Pure Appl. Chem., 1976, vol. 48, p. 127.

  23. Breck, D.W., Zeolites Molecular Sieves, New York: Wiley, 1974, p. 502.

    Google Scholar 

  24. Jain, A.K., Gupta, V.K., Singh, L.P., and Khurana, U., Electroanalysis, 1997, vol. 9, p. 1360.

    CAS  Google Scholar 

  25. Shamsipur, M., Rouhani, S., Mohajeri, A., Ganjali, M.R., and Rashidi, P.R., Anal. Chim. Acta, 2000, vol. 418, p. 197.

    Article  CAS  Google Scholar 

  26. Umezawa, Y., CRC Handbook of Ion-Selective Electrodes, Boca Raton (FL): CRC, 1990.

    Google Scholar 

  27. Bailey, P.L., Analysis with Ion-Selective Electrodes, London: Heyden, 1996.

    Google Scholar 

  28. Gadzepko, V.P. and Christian, G.D., Anal. Chim. Acta, 1984, vol. 164, p. 279.

    Google Scholar 

  29. Umezawa, Y., Umezawa, K., and Sato, H., Pure Appl. Chem., 1995, vol. 67, p. 507.

    Google Scholar 

  30. Bakker, E., Electroanalysis, 1997, vol. 9, p. 7.

    Article  CAS  Google Scholar 

  31. Kosswig, K. and Stache, H., Die Tenside, Wien: Carl Hanser, 1993.

    Google Scholar 

  32. Dilley, G.C., Analyst, 1980, vol. 105, p. 713.

    Article  CAS  Google Scholar 

  33. Selig, W., Fresenius J. Anal. Chem., 1980, vol. 300, p. 183.

    CAS  Google Scholar 

  34. Epton, S.R., Trans. Faraday Soc., 1948, vol. 44, p. 226.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Lahijan Islamic Azad University, P.O. Box 1616, Lahijan, Iran

    M. Giahi & A. M. Hejri

  2. Islamic Branch, Azad University, P.O. Box 14155/4933, Tehran, Iran

    H. Aghaie

  3. Guilan University, P.O. Box 1914, Rasht, Iran

    M. Arvand

Authors
  1. M. Giahi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Aghaie
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Arvand
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. M. Hejri
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to M. Giahi.

Additional information

__________

From Elektrokhimiya, Vol. 41, No. 12, 2005, pp. 1447–1453.

Original English Text Copyright © 2005 by Giahi, Aghaie, Arvand, Hejri.

The text was submitted by the authors in English.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Giahi, M., Aghaie, H., Arvand, M. et al. Application of a Zeolite-Poly(vinyl chloride) Electrode to Potentiometric Studies of Alkali Metal Ions. Russ J Electrochem 41, 1290–1295 (2005). https://doi.org/10.1007/s11175-005-0217-6

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11175-005-0217-6

Key words

Search

Navigation