Abstract
This work is devoted to a consideration of methods of electrochemical synthesis of redox polymers poly[M(Schiff)], where “M” is Ni, or Pd and “Schiff” stands for a four-dentate Schiff base, with a controlled distribution of structural elements (stacks) over the electrode's surface for the optimization of the transport of charge-compensating ions, which is the stage that determines the charge transfer rate in the system under consideration. It is shown that the structuring of these polymers on a molecular level by means of a purposeful selection of the composition of the initial compounds and the conditions of synthesis—the potential of formation and the nature of the solvent and supporting electrolyte—makes it possible to a considerable extent accelerate the charge transfer process in the polymers and improve stability of their electrochemical characteristics.
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Translated from Elektrokhimiya, Vol. 41, No. 10, 2005, pp. 1239–1248.
Original Russian Text Copyright © 2005 by Rodyagina, Gaman'kov, Dmitrieva, Chepurnaya, Vasil'eva, Timonov.
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Rodyagina, T.Y., Gaman'kov, P.V., Dmitrieva, E.A. et al. Structuring Redox Polymers Poly[M(Schiff)] (M = Ni, Pd; Schiff = Schiff Bases) on a Molecular Level: Methods and Results of an Investigation. Russ J Electrochem 41, 1101–1110 (2005). https://doi.org/10.1007/s11175-005-0188-7
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DOI: https://doi.org/10.1007/s11175-005-0188-7