Abstract
The synthesis of a composite membrane material on the basis of cation-exchange membrane MK-40 with inserted particles of acid zirconium phosphate is realized. It is shown that zirconium phosphate in the membrane's matrix takes on the form of small amorphous particles and is uniformly distributed. The obtained membrane is characterized by large values of conductance and diffusion coefficients for cations and anions, as well as by a lower selectivity when compared with the initial analogue. It is shown that the basic reason for this is the increase in the size of pores and channels, which are filled in the course of experiment by a solution of an electrolyte.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Yaroslavtsev, A.B., Nikonenko, V.V., and Zabolotskii, V.I., Usp. Khim., 2003, vol. 72, p. 438.
Nunes, S.P. and Peinemann, K.-V., Membrane Technology in Chemical Industry, Weinheim: Wiley-VCH, 2001.
Prater, K., J. Power Sources, 1994, vol. 51, p. 129.
Bonnet, B., Jones, D.J., Roziere, J., Tchicaya, L., Alberti, G., Casciola, M., Massinelli, L., Bauer, B., Peraio, A., and Ramunni, E., J. New Mater. Electrochem. Syst., 2000, vol. 3, p. 87.
Peled, E., Duvdevani, T., and Milman, A., Electrochem. Solid State Chem., 1998, vol. 1, p. 210.
Tazi, B. and Saadogo, O., Electrochim. Acta, 2000, vol. 45, p. 4329.
Kwak, S.-H., Yang, T.-H., Kim, C.-S., and Yoon, K.H., Solid State Ionics, 2003, vol. 160, p. 309.
Kim, K.M., Ko, J.M., Park, N.-G., Ryu, K.S., and Chang, S.H., Solid State Ionics, 2003, vol. 161, p. 121.
Damay, F. and Klein, L.C., Solid State Ionics, 2003, vol. 162–163, p. 261.
Deng, Q., Cable, K.M., Moore, R.B., and Mauritz, K.A., J. Polym. Sci., Part B: Polym. Phys., 1996, vol. 34, p. 1917.
Baradie, B., Dodelet, J.P., and Guay, D., J. Electroanal. Chem., 2000, vol. 489, p. 101.
Jones, D. and Roziere, J., Proc. XII Int. Conf. on Solid State Proton Conductors, Uppsala, 2004, p. 28.
Tret'yakov, Yu.D., Lukashin, A.V., and Eliseev, A.A., Usp. Khim., 2004, vol. 73, p. 974.
GOST (State Standard) 17553-72: Ion-Exchange Membranes: Methods of Preparation for Testing, 1972.
Belaid, N.N., Dammak, L., Ngom, B., Larchet, C., and Auclair, B., Eur. J. Polym, 1998, p. 564.
Volodina, E., Pismenskaya, N., Nikonenko, V., Larchet, C., and Pourcelly, G., J. Colloid Interface Sci. (in press.sciencedirect.com, jcis 10770).
Alberti, G., Casciola, M., and Costantino, U., J.Inorg. Nucl. Chem., 1978, vol. 40, p. 533.
Zabolotskii, V.I. and Nikonenko, V.V., Perenos ionov v membranakh (The Ion Transport in Membranes), Moscow: Nauka, 1996.
Damaskin, B.B., Petrii, O.A., and Tsirlina, G.A., Elektrokhimiya (Electrochemistry), Moscow: Khimiya, 2001, p. 124.
Larchet, C., Dammak, L., Auclair, B., Parchikov, S., and Nikonenko, V., New J. Chem., 2004, vol. 28, p. 1260.
Gnusin, N.P., Berezina, N.P., Shudrenko, A.A., and Ivina, O.P., Zh. Fiz. Khim., 1994, vol. 68, p. 565.
Helfferich, F., Ionenaustauscher, Weinheim: Chemie, 1959.
Zabolotskii, V.I., Shel'deshov, N.V., and Gnusin, N.P., Usp. Khim., 1988, vol. 57, p. 1403.
Pismenskaya, N., Nikonenko, V., Pourcelly, G., and Auclair, B., J. Membr. Sci., 2001, vol. 189, p. 129.
Author information
Authors and Affiliations
Corresponding author
Additional information
__________
Translated from Elektrokhimiya, Vol. 41, No. 10, 2005, pp. 1205–1211.
Original Russian Text Copyright © 2005 by Novikova, Volodina, Pis'menskaya, Veresov, Stenina, Yaroslavtsev.
Rights and permissions
About this article
Cite this article
Novikova, S.A., Volodina, E.I., Pis'menskaya, N.D. et al. Ionic Transport in Cation-Exchange Membranes MK-40 Modified with Zirconium Phosphate. Russ J Electrochem 41, 1070–1076 (2005). https://doi.org/10.1007/s11175-005-0183-z
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11175-005-0183-z