Skip to main content
SpringerLink
Log in

Impedance of the Ag|Nd0.95Sr0.05F2.95 Crystal|Ag System

  • Short Communications
  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Electrochemical studies of the Ag|Nd0.95Sr0.05F2.95 crystal|Ag system at 94 to 1072 K are carried out using impedance measurements over the 10−1 to 107 Hz frequency range. Contributions of conduction and bulk and electrode polarization are distinguished in the impedance spectra of the Ag| Nd0.95Sr0.05F2.95|Ag cell. Anionic conductivity of the Nd0.95Sr0.05F2.95 crystal varies from 3 × 10−13 to 0.4 S/cm. The mechanism of anionic conduction and models for the electrode and bulk polarization are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

REFERENCES

  1. Fergus, J.W., Sens. Actuators B, 1997, vol. 42, p. 119.

    Article  Google Scholar 

  2. Sorokin, N.I., Sudakova, E.F., Krivandina, E.A., and Sobolev, B.P., Elektrokhimiya, 1999, vol. 35, p. 246.

    Google Scholar 

  3. Sorokin, N.I. and Sobolev, B.P., Kristallografiya, 1994, vol. 39, p. 889.

    Google Scholar 

  4. Sorokin, N.I., Fominykh, M.V., Krivandina, E.A., Zhmurova, Z.I., and Sobolev, B.P., Kristallografiya, 1996, vol. 41, p. 310.

    Google Scholar 

  5. Sorokin, N.I., Fominykh, M.V., Krivandina, E.A., Zhmurova, Z.I., Fistul’, V.I., and Sobolev, B.P., Fiz. Tverd. Tela, 1999, vol. 41, p. 638.

    Google Scholar 

  6. Van de Pol Roos, A., Keim, R., and Schoonman, J., Solid State Ionics, 1984, vol. 13, p. 191.

    Article  Google Scholar 

  7. Sobolev, B.P., Aleksandrov, V.B., Fedorov, P.P., Seiranyan, K.B., and Tkachenko, N.L., Kristallografiya, 1976, vol. 21, p. 96.

    Google Scholar 

  8. Dygas, J.R. and Breiter, M.W., Electrochim. Acta, 1996, vol. 41, p. 993.

    Article  Google Scholar 

  9. Sorokin, N.I. and Breiter, M.W., Solid State Ionics, 1997, vol. 99, p. 241.

    Article  Google Scholar 

  10. Roos, A. and Schoonman, J., Solid State Ionics, 1984, vol. 13, p. 205.

    Article  Google Scholar 

  11. Murin, I.V., Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk, 1984, p. 53.

  12. Takahashi, T., Iwahara, H., and Ishikawa, T., J. Electrochem. Soc., 1977, vol. 124, p. 280.

    Google Scholar 

  13. Izosimova, M.G., Livshits, A.I., Buznik, V.M., Fedorov, P.P., Krivandina, E.A., and Sobolev, B.P., Fiz. Tverd. Tela, 1986, vol. 28, p. 2644.

    Google Scholar 

  14. Denecke, M.A., Gunsser, W., Privalov, A.V., and Murin, I.V., Solid State Ionics, 1992, vol. 52, p. 327.

    Article  Google Scholar 

  15. Wang, F. and Grey, P., Chem. Mater., 1997, vol. 9, p. 1068.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333, Russia

    N. I. Sorokin

Authors
  1. N. I. Sorokin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. I. Sorokin.

Additional information

__________

Translated from Elektrokhimiya, Vol. 41, No. 8, 2005, pp. 1005–1009.

Original Russian Text Copyright © 2005 by Sorokin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sorokin, N.I. Impedance of the Ag|Nd0.95Sr0.05F2.95 Crystal|Ag System. Russ J Electrochem 41, 896–899 (2005). https://doi.org/10.1007/s11175-005-0152-6

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11175-005-0152-6

Key words

Search

Navigation