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Method for Thermodynamic Description of an Elastically Deformed Electrode, Based on Relating Its Extensive Surface Characteristics to a Strainless Electrode

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Abstract

A theoretical approach to thermodynamic describing elastically deformed electrodes made of isotropic materials is suggested. The approach is based on considering the surface of a strainless electrode as a reference one. A surface analog of the Lame elastic constants is introduced. Dependences of the Shuttleworth equation and the Gibbs adsorption equation on the Lame elastic constants characterizing the surface are found in an explicit form.

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REFERENCES

  1. Shuttleworth, R., Proc. Phys. Soc. A, 1950, vol. 63, p. 444.

    Article  Google Scholar 

  2. Frumkin, A.N., Petry, O.A., and Damaskin, B.B., J. Electroanal. Chem., 1972, vol. 35, p. 439.

    Article  Google Scholar 

  3. Linford, R.G., J. Electroanal. Chem., 1973, vol. 43, p. 155.

    Article  Google Scholar 

  4. Gokhshtein, A.Ya., Poverkhnostnoe natyazhenie tverdykh tel i adsorbtsiya (Surface Stress in Solids and Adsorption), Moscow: Nauka, 1976.

    Google Scholar 

  5. Couchman, P.R. and Everett, D.H., J. Electroanal. Chem., 1976, vol. 67, p. 382.

    Article  Google Scholar 

  6. Linford, R.G., Chem. Rev., 1978, vol. 78, p. 81.

    Article  Google Scholar 

  7. Paasch, G. and Hitschold, M., Ergebnisse in der Elektronentheorie der Metalle, Ziesche, P. and Lehmann, G., Eds., Berlin: Akademie, 1983, ch. 10.

    Google Scholar 

  8. Trasatti, S. and Parsons, R., Pure Appl. Chem., 1986, vol. 58, p. 451.

    Google Scholar 

  9. Lang, G. and Heusler, K.E., J. Electroanal. Chem., 1994, vol. 377, p. 1.

    Article  Google Scholar 

  10. Lipkowski, J., Schmickler, W., Kolb, D.M., and Parsons, R., J. Electroanal. Chem., 1998, vol. 452, p. 193.

    Article  Google Scholar 

  11. Haiss, W., Nichols, R.J., Saas, J.K, and Charle, K.P., J. Electroanal. Chem., 1998, vol. 542, p. 199.

    Google Scholar 

  12. Schmickler, W. and Leiva, E., J. Electroanal. Chem., 1998, vol. 453, p. 61.

    Article  Google Scholar 

  13. Guidelli, R., J. Electroanal. Chem., 1998, vol. 453, p. 69.

    Article  Google Scholar 

  14. Grafov, B.M., J. Electroanal. Chem., 1999, vol. 471, p. 105.

    Article  Google Scholar 

  15. Valincius, G., J. Electroanal. Chem., 1999, vol. 478, p. 40.

    Article  Google Scholar 

  16. Grafov, B.M., Elektrokhimiya, 1999, vol. 35, p. 1173.

    Google Scholar 

  17. Grafov, B.M., Paasch, G., Plieth, W., and Bund, A., Electrochim. Acta, 2002, vol. 48, p. 581.

    Article  Google Scholar 

  18. Sokolnikoff, I.S., Mathematical Theory of Elasticity, New York: McGraw-Hill, 1956.

    Google Scholar 

  19. Landau, L.D. and Lifshits, E.M., Teoriya uprugosti (Theory of Elasticity), Moscow: Nauka, 1956.

    Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    B. M. Grafov

  2. Leibniz Institute for Solid State and Materials Research, Dresden, PF 270016, D-01171 Dresden, Germany

    G. Paasch

Authors
  1. B. M. Grafov
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  2. G. Paasch
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Correspondence to B. M. Grafov.

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Translated from Elektrokhimiya, Vol. 41, No. 8, 2005, pp. 993–996.

Original Russian Text Copyright © 2005 by Grafov, Paasch.

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Grafov, B.M., Paasch, G. Method for Thermodynamic Description of an Elastically Deformed Electrode, Based on Relating Its Extensive Surface Characteristics to a Strainless Electrode. Russ J Electrochem 41, 885–887 (2005). https://doi.org/10.1007/s11175-005-0149-1

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  • DOI: https://doi.org/10.1007/s11175-005-0149-1

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