Abstract
The frequency dependence of the transfer function of an electrochemical cell is studied experimentally and theoretically in the frequency region 0.005 to 1 Hz under conditions of controlled convective diffusion, at various boundary conditions on the anodes. It is shown that the results are independent of the conditions on the anodes at frequencies exceeding a diffusion frequency. On the other hand, the effect of the boundary conditions al low frequencies is substantial. In particular, it is shown that it is feasible to design a cell with a conversion efficiency indefinitely increasing in the direction of lower frequencies.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Larcam, C.W., J. Acoust. Soc. Am., 1965, vol. 37, p. 664.
Kozlov, V.A. and Terent’ev, D.A., Elektrokhimiya, 2002, vol. 38, p. 1104.
Kozlov, V.A. and Terent’ev, D.A., Elektrokhimiya, 2003, vol. 39, p. 443.
Vyaselev, M.R., Miftakhov, A.G., and Sultanov, E.I., Elektrokhimiya, 2002, vol. 38, p. 239.
Zakharov, I.S. and Kozlov, V.A., Elektrokhimiya, 2003, vol. 39, p. 438.
Babanin, A.V., Kozlov, V.A., and Pet’kin, N.V., Elektrokhimiya, 1990, vol. 26, p. 601.
Newman, J.S., Electrochemical Systems, New York: Prentice-Hall, 1973.
Agafonov, V.M., Abramovich, I., and Daragan, S.K., Seism. Res. Lett., 1996, vol. 67, p. 34.
Author information
Authors and Affiliations
Corresponding author
Additional information
__________
Translated from Elektrokhimiya, Vol. 41, No. 8, 2005, pp. 987–992.
Original Russian Text Copyright © 2005 by Agafonov, Nesterov.
Rights and permissions
About this article
Cite this article
Agafonov, V.M., Nesterov, A.S. Convective Current in a Four-Electrode Electrochemical Cell at Various Boundary Conditions at Anodes. Russ J Electrochem 41, 880–884 (2005). https://doi.org/10.1007/s11175-005-0148-2
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11175-005-0148-2