Abstract
The rate of anodic oxidation of the hypophosphite ion on alloys Ni-P, Ni-B, and Ni-Mo-P is studied as a function of their composition and structure. The organic compounds that are customarily used to stabilize electrolytes of electroless nickel plating are shown to come useful when controlling composition of the Ni-P coatings at the expense of their different influence on the rates of partial processes of deposition of the alloy components. The formation of catalytic activity of such coatings is affected mostly by a structural factor. With alloys Ni-P, Ni-B, and Ni-Mo-P, whose composition was varied by altering the concentration of the source of the alloying component, dependence of catalytic activity of the surface on the composition is defined mainly by an electronic factor.
Similar content being viewed by others
REFERENCES
Shervedani, R.K. and Lasia, A., J. Electrochem. Soc., 1997, vol. 144, p. 511.
Lu, G., Evans, P., and Zangari, G., J. Electrochem. Soc., 2003, vol. 150, p. A551.
Paseka, I. and Velicka, J., Electrochim. Acta, 1997, vol. 42, p. 231.
Krolikowski, A., Wiecko, A., Electrochim. Acta, 2002, vol. 47, p. 2065.
Miaomiao, M., Donepudi, V.S., Sandi, G., Sunc, Y.K., and Drakash, J., Electrochim. Acta, 2004, vol. 49, p. 4411.
Abdel Rahim, M.A., Abdel Hameed, R.M., and Khalil, M.W., J. Power Sources, 2004, vol. 134, p. 160.
Gorbunova, K.M., Zh. Vses. Khim. O-va im. D.I. Mendeleeva, 1980, vol. 25, p. 175.
Sotskaya, N.V., Goncharova, L.G., Kravchenko, T.A., and Zhivotova, E.V., Elektrokhimiya, 1997, vol. 33, p. 529.
Shcheblykina, G.E., Bobrinskaya, E.V., and Vvedenskii, A.V., Zashch. Met., 1998, vol. 34, p. 11.
Khaldeev, G.V., Petukhov, I.V., and Shcherban’, M.G., Elektrokhimiya, 2000, vol. 36, p. 1062.
Zhenga, Y. and Zhoub, S., Electrochem. Commun., 1999, vol. 1, p. 217.
Zeng, Y., Zhenga, Y., and Yua, S., Electrochem. Commun., 2002, vol. 4, p. 293.
Jaksis, M.M., Int. J. Hydrogen Energy, 1987, p. 727.
Sotskaya, N.V., Ryabinina, E.I., Kravchenko, T.A., and Shikhaliev, Kh.S., Zashch. Met., 2003, vol. 39, p. 276.
Sotskaya, N.V., Ryabinina, E.I., Kravchenko, T.A., and Shikhaliev, Kh.S., Zashch. Met., 2003, vol. 39, p. 281.
Neiland, O.Ya., Organicheskaya khimiya (Organic Chemistry), Moscow: Vysshaya Shkola, 1990.
Gyanutene, I. and Lyankaitene, Yu., Zashch. Met., 1996, vol. 32, p. 648.
Hamilton, J.F. and Baetzold, R.C., Science, 1979, vol. 205, p. 4412.
Sotskaya, N.V., Kravchenko, T.A., Ryabinina, E.I., and Bocharova, O.V., Elektrokhimiya, 2003, vol. 39, p. 1074.
Povetkin, V.V., Kovenskii, I.M., and Ustinovshchikov, Yu.I., Struktura i svoistva elektroliticheskikh splavov (The Structure and Properties of Electrolytic Alloys), Moscow: Nauka, 1992, p. 71.
Author information
Authors and Affiliations
Corresponding author
Additional information
__________
Translated from Elektrokhimiya, Vol. 41, No. 8, 2005, pp. 972–980.
Original Russian Text Copyright © 2005 by Sotskaya, Dolgikh, Ryabinina.
Rights and permissions
About this article
Cite this article
Sotskaya, N.V., Dolgikh, O.V. & Ryabinina, E.I. Catalytic Activity of Nickel Alloys in Anodic Oxidation of the Hypophosphite Ion as a Function of Their Composition. Russ J Electrochem 41, 866–873 (2005). https://doi.org/10.1007/s11175-005-0146-4
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s11175-005-0146-4