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On the asymmetry of thermodynamic fluctuations of the electrode potential

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Abstract

The asymmetry of thermodynamic fluctuations of the equilibrium electrode potential and the asymmetry of thermodynamic fluctuations of the electrical double layer charge is characterized quantitatively on the basis of third-order noise spectra.

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REFERENCES

  1. Schultse, J.W. and Staikov, G., Electrochim. Acta, 2003, vol. 48, p. 2851.

    Google Scholar 

  2. Ito, Ya., J. Electroanal. Chem., 2003, vol. 559, p. 1.

    Google Scholar 

  3. Rudoi, Yu.G. and Sukhanov, A.D., Usp. Fiz. Nauk, 2000, vol. 170, p. 1265.

    Google Scholar 

  4. The Collected Works of J. Willard Gibbs, New Haven: Yale Univ. Press, 1948, vols. 1 and 2.

  5. Einstein, A., Izbrannye Sochineniya (Selected Opuses), Moscow: Nauka, 1966, vol. 3.

    Google Scholar 

  6. Landau, L.D. and Lifshits, E.M., Statisticheskaya fizika (Statistical Physics), Moscow: Nauka, 1964, pp. 412, 463.

    Google Scholar 

  7. Nyquist, H., Phys. Rev., 1928, vol. 32, p. 110.

    Google Scholar 

  8. Callen, H.B. and Welton, T.A., Phys. Rev., 1951, vol. 83, p. 34.

    Google Scholar 

  9. Bernard, W. and Callen, H.B., Rev. Mod. Phys., 1959, vol. 31, p. 1017.

    Google Scholar 

  10. Myunster, A., Termodinamika neobratimykh protsessov (Thermodynamics of Irreversible Processes), Moscow: Inostrannaya Literatura, 1962, p. 36.

    Google Scholar 

  11. Mak-Kombi, K., Zadachi po termodinamike i statisticheskoi fizike (Problems in Thermodynamics and Statistical Physics), Landsberg, P., Ed., Moscow: Mir, 1974.

    Google Scholar 

  12. Freeman, J.J., Principles of Noise, New York: Wiley, 1958.

    Google Scholar 

  13. Gupta, M.S., Proc. IEEE, 1982, vol. 70, p. 788.

    Google Scholar 

  14. Van Kampen, N.G., Stochastic Processes in Physics and Chemistry, Amsterdam: North-Holland Physics, 1984.

    Google Scholar 

  15. Van Kampen, N.G., J. Math. Phys., 1963, vol. 4, p. 190.

    Google Scholar 

  16. Yakimov, A.V., Belyakov, A.V., Petrov, M. Yu., and Vandamme, L.K.J., Proc. SPIE, 2003, vol. 5115, p. 40.

    Google Scholar 

  17. Smulko, J.M. and Kish, L.B., Proc. SPIE, 2003, vol. 5115, p. 92.

    Google Scholar 

  18. Yakimov, A.V., Belyakov, A.V., Moryashin, A.V., and Perov, M.Yu., Proc. 17 Int. Conf. on Noise and Fluctuations, Sikula, J., Ed., Prague, 2003, p. 71.

  19. Grafov, B.M., Proc. SPIE, 2003, vol. 5115, p. 16.

    Google Scholar 

  20. Grafov, B.M., Proc. 17 Int. Conf. on Noise and Fluctuations, Sikula, J., Ed., Prague, 2003, p. 41.

  21. Grafov, B.M., Elektrokhimiya, 2003, vol. 39, p. 469.

    Google Scholar 

  22. Grafov, B.M., Elektrokhimiya, 2003, vol. 39, p. 1116.

    Google Scholar 

  23. Stratonovich, R.L., Izv. Vyssh. Uchebn. Zaved., Radiofizika, 1970, vol. 13, p. 1512.

    Google Scholar 

  24. Malakhov, A.I., Kumulyantnyi analiz sluchainykh negaussovskikh protsessov i ikh preobrazovanii (A Cumulant Analysis of Random Non-Gaussian Processes and Their Transforms), Moscow: Sovetskoe Radio, 1978.

    Google Scholar 

  25. Rosenblatt, M. and Van Ness, J.W., Ann. Math. Stat., 1965, vol. 36, p. 1120.

    Google Scholar 

  26. Brillinger, D.R., Ann. Math. Stat., 1965, vol. 36, p. 1351.

    Google Scholar 

  27. Korn, G.A. and Korn, T.M., Mathematical Handbook, New York: McGraw-Hill, 1968.

    Google Scholar 

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Authors and Affiliations

  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, 119071, Moscow, Russia

    B. M. Grafov

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  1. B. M. Grafov
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Translated from Elektrokhimiya, Vol. 41, No. 2, 2005, pp. 131–136.

Original Russian Text Copyright © 2005 by Grafov.

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Grafov, B.M. On the asymmetry of thermodynamic fluctuations of the electrode potential. Russ J Electrochem 41, 113–117 (2005). https://doi.org/10.1007/s11175-005-0022-2

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  • DOI: https://doi.org/10.1007/s11175-005-0022-2

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