Skip to main content
SpringerLink
Log in

Study of the “Diamond—Pyrolytic Carbon” nanocomposites using lithium intercalation

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Electrochemical behavior of the diamond-based composites: a nanodiamond—pyrocarbon composite and Carbal, as well as vacuum-high-temperature-annealed polycrystalline diamond is studied by the cathodic lithium incorporation from LiPF 6 solution in a (1 : 4) propylene carbonate—diethyl carbonate mixture. The amount of incorporated lithium steadily increases with the nondiamond (graphite-like) carbon content in the composite. The intercalation capacity of Carbal equals ~33 mA-h per g of the graphite-like carbon. It is concluded that the graphite-like carbon distributed in the nano-(or micro-)diamond carcass is the electrochemically active phase in the composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. S.K. Gordeev (2001) NoChapterTitle G. Benedek P. Milani V.G. Ralchenko (Eds) Nanostructured Carbon for Advanced Applications Kluwer Dordrecht 71

    Google Scholar 

  2. A.M. Skundin O.N. Efimov O.V. Yarmolenko (2002) Usp. Khim. 71 378

    Google Scholar 

  3. G.V. Zhutaeva K.A. Radyushkina M.A. Marinich G.P. Bogatyreva M.A. Tarasevich (2001) Elektrokhimiya 37 1223

    Google Scholar 

  4. E.P. Smirnov S.K. Gordeev Yu. I. Nikitin V.G. Poltoratskii N.V. Novikov V.B. Aleskovskii (1984) Dokl. Akad. Nauk SSSR 274 887

    Google Scholar 

  5. Yu. V. Pleskov M.D. Krotova V.G. Ralchenko A.V. Khomich R.A. Khmel’nitskii (2003) Elektrokhimiya 39 886

    Google Scholar 

  6. O.V. Komarova T.L. Kulova A.M. Skundin (2002) Elektrokhim. Energ. 2 121

    Google Scholar 

  7. N.G. Ferreira L.L. Mendonca V.J.T. Airoldi J.M. Rosolen (2003) Diamond Related Mater. 12 596

    Google Scholar 

  8. A.V. Karabutov V.D. Frolov V.I. Konov V.G. Ralchenko S.K. Gordeev P.I. Belobrov (2001) J. Vac. Sci. Technol. Ser. B 19 965

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Russian Academy of Sciences, Frumkin Institute of Electrochemistry, Leninskii pr. 31, 119071, Moscow, Russia

    Y. V. Pleskov, T. L. Kulova, A. M. Skundin & M. D. Krotova

  2. Russian Academy of Sciences, Prokhorov Institute of General Physics, ul. Vavilova 38, 117942, Moscow, Russia

    V. G. Ral’chenko

  3. Central Research Institute of Materials, St. Petersburg, Russia

    S. B. Korchagina & S. K. Gordeev

Authors
  1. Y. V. Pleskov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. L. Kulova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Skundin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. D. Krotova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. G. Ral’chenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. S. B. Korchagina
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. S. K. Gordeev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Elektrokhimiya, Vol. 40, No. 12, 2004, pp. 1508–1513.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pleskov, Y.V., Kulova, T.L., Skundin, A.M. et al. Study of the “Diamond—Pyrolytic Carbon” nanocomposites using lithium intercalation. Russ J Electrochem 40, 1292–1297 (2004). https://doi.org/10.1007/s11175-005-0007-1

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11175-005-0007-1

Key words

Search

Navigation