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Kinetics and mechanism of electroreduction of Pd(II) complexes

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Abstract

The kinetics and mechanism of processes of reduction of Pd(II) complexes with a number of inorganic (NH3 , Cl− , etc.) and organic (ethylenediamine, glycine, α-alanine, etc.) ligands on a dropping-mercury electrode and a Pd electrode in solutions with various concentrations of ligands, hydrogen ions, and supporting electrolytes are reviewed. The nature of electrochemical and chemical steps of processes of reduction of various complexes of Pd(II) is discussed.

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Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, Petrodvorets, 198054, St. Petersburg, Russia

    V. I. Kravtsov

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  1. V. I. Kravtsov
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Translated from Elektrokhimiya, Vol. 40, No. 12, 2004, pp. 1494–1502.

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Kravtsov, V.I. Kinetics and mechanism of electroreduction of Pd(II) complexes. Russ J Electrochem 40, 1278–1286 (2004). https://doi.org/10.1007/s11175-005-0005-3

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  • DOI: https://doi.org/10.1007/s11175-005-0005-3

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