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Complexation of D-Xylose and L-Arabinose with 18-Crown-6 in Aqueous Solutions: Calorimetric, Densimetric, and Viscometric Studies

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Abstract

Capability of L-arabinose and D-xylose to form molecular complexes with 18-crown-6 in aqueous solutions was studied by calorimetric titration, densitometry, and viscometry methods. Unlike D-xylose, L-arabinose was found to give thermodynamically stable complex with crown ether, which is likely to be due to peculiar stereochemical properties of monosaccharide molecules.

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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 12, 2005, pp. 946–950.

Original Russian Text Copyright © 2005 by Volkova, Lebedeva, Parfenyuk.

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Volkova, N.L., Lebedeva, N.S. & Parfenyuk, E.V. Complexation of D-Xylose and L-Arabinose with 18-Crown-6 in Aqueous Solutions: Calorimetric, Densimetric, and Viscometric Studies. Russ J Coord Chem 31, 899–903 (2005). https://doi.org/10.1007/s11173-005-0189-9

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  • DOI: https://doi.org/10.1007/s11173-005-0189-9

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