Abstract
Specific features of the acid-base interaction of tetra(4-tert-butyl)phthalocyanine with cyclic and acyclic nitrogen-containing bases in dimethyl sulfoxide are studied. The effect of pK a of proton-withdrawing molecules, basicity of a medium, and steric screening of acidic NH centers on the kinetic parameters of formation of proton-transfer complexes stable in time is shown.
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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 12, 2005, pp. 941–945.
Original Russian Text Copyright © 2005 by Petrov, Osipova, Semeikin, Berezin.
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Petrov, O.A., Osipova, G.V., Semeikin, A.S. et al. Kinetics of the Acid-Base Interaction between Tetra(4-tert-butyl)phthalocyanine and Nitrogen-Containing Bases in Dimethyl Sulfoxide. Russ J Coord Chem 31, 894–898 (2005). https://doi.org/10.1007/s11173-005-0188-x
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DOI: https://doi.org/10.1007/s11173-005-0188-x