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Synthesis and Properties of Double Complex Salts Containing the Cation [Co(NH3)6]3+

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Abstract

A series of complexes [Co(NH3)6] x [ML6(4)] y , where M is Fe(III) and Fe(II), Cr(III), Cu(II); L is CN−, NCS−, 1/2C2O 2−4 , are synthesized. Their IR spectra and thermal decomposition in air are studied, and interplanar distances in crystalline lattices of the complexes are determined. The compounds can be used as precursors for producing homogeneous bimetallic nanodimensional powders.

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Authors and Affiliations

  1. Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center, Russian Academy of Sciences, ul. Fersmana 14, Apatity, Murmansk oblast, 184200, Russia

    S. I. Pechenyuk, Yu. P. Semushina, G. I. Kadyrova, D. L. Rogachev, L. F. Kuz'mich, D. P. Domonov & V. T. Kalinnikov

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  1. S. I. Pechenyuk
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  2. Yu. P. Semushina
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  3. G. I. Kadyrova
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  4. D. L. Rogachev
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  5. L. F. Kuz'mich
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  6. D. P. Domonov
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  7. V. T. Kalinnikov
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__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 12, 2005, pp. 912–917.

Original Russian Text Copyright © 2005 by Pechenyuk, Semushina, Kadyrova, Rogachev, Kuz'mich, Domonov, Kalinnikov.

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Pechenyuk, S.I., Semushina, Y.P., Kadyrova, G.I. et al. Synthesis and Properties of Double Complex Salts Containing the Cation [Co(NH3)6]3+ . Russ J Coord Chem 31, 866–871 (2005). https://doi.org/10.1007/s11173-005-0183-2

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  • DOI: https://doi.org/10.1007/s11173-005-0183-2

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