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Synthesis of 5,6-O-Cyclohexylidene-1-amino-3-azahexane and Its Co(II), Ni(II), Cu(II) Complexes

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Abstract

5,6-O-Cyclohexylidene-1-amino-3-azahexane (L) is synthesized from 1-chloro-2,3-O-cyclohexylidenepropane, which is prepared by the reaction between epichlorohydrin and cyclohexanone. In this reaction, BF3 · OEt2 is used as a catalyst. Complexes of Co(II), Ni(II) and Cu(II) acetates with this ligand are prepared. The structures of the ligand and its complexes are proposed based on elemental analysis, IR and UV-VIS spectroscopy, magnetic susceptibility, conductometry, and 1H and 13C NMR spectroscopy.

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Authors and Affiliations

  1. Faculty of Arts and Sciences, Chemistry Department, Canakkale Onsekiz Mart University, Canakkale, Turkey

    O. F. Ozturk & E. Ozdemir

  2. Faculty of Arts and Sciences, Chemistry Department, Firat University, Elazig, Turkey

    M. Sekerci

Authors
  1. O. F. Ozturk
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  2. M. Sekerci
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  3. E. Ozdemir
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__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 9, 2005, pp. 687–690.

Original Russian Text Copyright © 2005 by Ozturk, Sekerci, Ozdemir.

The text was submitted by the authors in English.

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Ozturk, O.F., Sekerci, M. & Ozdemir, E. Synthesis of 5,6-O-Cyclohexylidene-1-amino-3-azahexane and Its Co(II), Ni(II), Cu(II) Complexes. Russ J Coord Chem 31, 651–654 (2005). https://doi.org/10.1007/s11173-005-0150-y

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  • DOI: https://doi.org/10.1007/s11173-005-0150-y

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