Abstract
4,4′-Bis(chloroacetyl)diphenyl ether (HL) was synthesized from chloroacetyl chloride and diphenyl ether in the presence of AlCl3 as catalyst by Friedel-Crafts reaction. Subsequently, its keto oxime (H2L) and glyoxime (H4L) derivatives were also prepared. Then, five new substituted 4,4′-oxy-bis(aminophenyl-glyoximes) (H4L1–5) were synthesized from 4,4′-oxy-bis(chlorophenylglyoxime) and the corresponding amines. The Ni(II), Cu(II), and Co(II) complexes of these ligands were prepared. The structures of these ligands and their complexes were identified by FT-IR, 1H NMR, and ICP-AES spectral data, elemental analyses, and magnetic measurements.
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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 9, 2005, pp. 681–686.
Original Russian Text Copyright © 2005 by Coskun, Karatas.
The text was submitted by the authors in English.
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Coskun, A., Karatas, I. Synthesis of Substituted 4,4′-Oxy-bis(aminophenylglyoximes) and Their Polymeric Metal Complexes with Cu(II), Ni(II), and Co(II) Salts. Russ J Coord Chem 31, 645–650 (2005). https://doi.org/10.1007/s11173-005-0149-4
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DOI: https://doi.org/10.1007/s11173-005-0149-4