Skip to main content
SpringerLink
Log in

Structure of Ba Na Ethylenediaminetetraacetatocobaltate(III) Perchlorate, Na[Ba6(H2O)25][Co(Edta)]4(ClO4)9 · 5H2O

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Crystals with uncommon composition NaBa6[Co(Edta)]4(ClO4)9 · 30H2O (Edta4− is ethylenediaminetetraacetic acid anion) were obtained with the following unit cell parameters: a = 14.8513(9) Å, b = 26.2361(15) Å, c = 15.1789(9) Å, α = 91.661(7)°, β = 113.035(7)°, γ = 89.897(7)°, space group P1¯. Each complex anion [Co(Edta)]− is bonded through the carboxyl O atoms to five Ba atoms to give three-dimensional framework in a crystal. One perchlorate ion forms Ba-O-Cl-O-Ba bridge between the Ba atoms; four ClO −4 ions are isolated, while the remaining four ions act as monodentate ligands at the Ba atoms. The water molecules (25 in sum) complete the coordination sphere of the Ba atoms to eight-, nine-, or ten-vertex polyhedron. Four water molecules are in the closest surrounding of the Na atom, one H2O molecule is isolated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Serezhkin, V.N, Polynova, T.N., and Porai-Koshits, M.A., Koord. Khim., 1995, vol. 21, no.4, p. 253.

    Google Scholar 

  2. Porai-Koshits, M.A. and Serezhkin, V.N., Zh. Neorg. Khim., 1994, vol. 39, no.12, p. 1967.

    Google Scholar 

  3. Chuklanova, E.B., Polynova, T.N., Poznyak, A.L., et al., Koord. Khim., 1981, vol. 7, no.11, p. 1729.

    Google Scholar 

  4. Polyakova, I.N., Sergienko, V.S., and Poznyak, A.L., Zh. Neorg. Khim., 1995, vol. 40, no.11, p. 1811.

    Google Scholar 

  5. Chuklanova, E.B., Polynova, T.N., Porai-Koshits, M.A., and Poznyak, A.L., Koord. Khim., 1988, vol. 14, no.8, p. 1115.

    Google Scholar 

  6. Gladkikh, O.P., Polynova, T.N., Porai-Koshits, M.A., and Poznyak, A.L., Koord. Khim., 1992, vol. 18, nos. 10–11, p. 1156.

    Google Scholar 

  7. Obodovskaya, A.E., Poznyak, A.L., and Shkol’nikova, L.M., Koord. Khim., 1994, vol. 20, no.7, p. 508.

    Google Scholar 

  8. Ogino, H. and Ogino E., Inorg. Chem., 1983, vol. 22, no.15, p. 2208.

    Article  Google Scholar 

  9. Altomare, A., Burla, M.C., Carnalli, M., et al., J. Appl. Crystallogr., 1999, vol. 32, no.1, p. 115.

    Article  Google Scholar 

  10. Sheldrick, G.M., SHELXL97. Program for Crystal Structure Refinement, Gottingen, 1997.

  11. Spek, A.L., J. Appl. Crystallogr., 2003, vol. 36, no.1, p. 7.

    Article  Google Scholar 

  12. Okazaki, H., Tomioka, K., and Yoneda, H., Inorg. Chim. Acta, 1983, vol. 74, no.1, p. 169.

    Article  Google Scholar 

  13. Zasurskaya, L.A., Poznyak, A.L., Polynova, T.N., et al., Zh. Neorg. Khim., 1996, vol. 41, no.10, p. 1647 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 41, no. 10, p. 1569].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute fur Anorganishe Chemie Universitat Regensburg, Germany

    M. Zabel

  2. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, Minsk, Belarus

    A. L. Poznyak & V. I. Pawlowski

Authors
  1. M. Zabel
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. L. Poznyak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. I. Pawlowski
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 8, 2005, pp. 590–595.

Original Russian Text Copyright © 2005 by Zabel, Poznyak, Pawlowski.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zabel, M., Poznyak, A.L. & Pawlowski, V.I. Structure of Ba Na Ethylenediaminetetraacetatocobaltate(III) Perchlorate, Na[Ba6(H2O)25][Co(Edta)]4(ClO4)9 · 5H2O. Russ J Coord Chem 31, 559–564 (2005). https://doi.org/10.1007/s11173-005-0136-9

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11173-005-0136-9

Keywords

Search

Navigation