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Complex Formation on the Surface of Tungsten on Its Chlorination in DMF Medium

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Abstract

IR spectroscopy and chromato-mass spectrometry were used to investigate the surface layer of tungsten after its chlorination in a medium of DMF containing water. The mechanism of this process is similar to that of the previously described chlorination of rhenium and molybdenum and is determined by the participation of a complex formed in the DMF-H2O-Cl2 system.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. N. Trifonova, A. A. Mukhanova, A. I. Stepanov, N. F. Drobot & V. A. Krenev

  2. Lomonosov Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571, Russia

    D. V. Drobot

Authors
  1. E. N. Trifonova
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  2. A. A. Mukhanova
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  3. A. I. Stepanov
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  4. N. F. Drobot
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  5. V. A. Krenev
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  6. D. V. Drobot
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__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 6, 2005, pp. 436–440.

Original Russian Text Copyright © 2005 by Trifonova, Mukhanova, Stepanov, N. Drobot, Krenev, D. Drobot.

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Trifonova, E.N., Mukhanova, A.A., Stepanov, A.I. et al. Complex Formation on the Surface of Tungsten on Its Chlorination in DMF Medium. Russ J Coord Chem 31, 410–414 (2005). https://doi.org/10.1007/s11173-005-0112-4

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  • DOI: https://doi.org/10.1007/s11173-005-0112-4

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