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Complexation of Heteropoly Anion [MnMo9O32]6− with Lanthanide Ions

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Abstract

The properties of [MnMo9O32]6− heteropoly anion (HPA 1), as a macroligand with respect to the lanthanide ions, were studied. The band due to heteronuclear charge transfer Ce(III)4f → Mo(VI)4d was isolated. The crystal structure of heteropoly complex (HPC) [La2(H2O)12 (MnMo9O32)] ⋅ 2H2O (I) was determined (space group B2/n, a = 23.597(2) Å, b = 19.832(1) Å, c = 11.810(1) Å, γ = 132.390(6)°, V = 4083.4(6) Å3, Z = 4, R = 3.4%). In HPC, the [MnMo9O32]6− ligand (HPA 1) is a hexadentate ligand, which provides for coordination with each of the two La3+ ions three terminal O atoms of the cis-MoO2 groups. This HPC is peculiar in its neutrality and in the cis-position of the coordination active centers on the ligand surface. The coordination polyhedron of the La atom (nine-vertex polyhedron) is formed by three terminal O atoms of HPA1 and by six O atoms of water molecules. IR study revealed that the terminal O atoms of the cis-MoO2 groups of a ligand are involved in coordination with La.

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Authors and Affiliations

  1. Belgorod Research Institute of Agriculture, Russian Academy of Agricultural Sciences, Belgorod, Russia

    L.O. Gavrilova

  2. Institute of Crystallography, Russian Academy of Sciences, Leninskii pr. 59, Moscow, 117333, Russia

    V. N. Molchanov

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  1. L.O. Gavrilova
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  2. V. N. Molchanov
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__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 6, 2005, pp. 427–435.

Original Russian Text Copyright © 2005 by Gavrilova, Molchanov.

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Gavrilova, L., Molchanov, V.N. Complexation of Heteropoly Anion [MnMo9O32]6− with Lanthanide Ions. Russ J Coord Chem 31, 401–409 (2005). https://doi.org/10.1007/s11173-005-0111-5

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  • DOI: https://doi.org/10.1007/s11173-005-0111-5

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