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To Interpretation of the EPR Parameters of Nitrosyl Complexes of Transition Metal Ions

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Abstract

Interpretation of the EPR parameters of low-spin nitrosyl complexes of d 5 transition metal ions was illustrated with a pentacyanonitrosyl complex of Cr+. The bond covalence in the antibonding and bonding states of this complex was determined from EPR and optical spectroscopic data. The reasons for the observed abnormal value of the Zeeman splitting parameter were analyzed. The contributions to the components of the A and HFC tensors at the N atom of the nitrosyl group were calculated.

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REFERENCES

  1. Fortman, J.J. and Hayes, R.G., J. Chem. Phys., 1965, vol. 43, no.1, p. 15.

    Article  CAS  Google Scholar 

  2. Danon, J., Panepucci, H., and Misetich, A.A., J. Chem. Phys., 1966, vol. 44, no.11, p. 4154.

    Article  CAS  Google Scholar 

  3. Murav’ev, V.I., Zh. Strukt. Khim., 1982, vol. 23, no.5, p. 166.

    CAS  Google Scholar 

  4. Marov, I.N., Dubrov, Yu.N., Belyaeva, V.K., and Ermakov, A.N., Zh. Neorg. Khim., 1972, vol. 17, no.8, p. 2666.

    CAS  Google Scholar 

  5. Murav’ev, V.I., Koord. Khim., 2004, vol. 30, no.2, p. 87.

    Google Scholar 

  6. McGarvey, B.R., Transit. Metal Chem., New York: Dekker, 1966, vol. 3, p. 89.

    Google Scholar 

  7. Murav’ev, V.I. and Stepanov, V.G., Koord. Khim., 1984, vol. 10, no.11, p. 1467.

    CAS  Google Scholar 

  8. Murav’ev, V.I., Koord. Khim., 1989, vol. 15, no.10, p. 1314.

    CAS  Google Scholar 

  9. Kuska, H.A. and Rogers, M.T., Electron Spin Resonance of First Row Transition Metal Complex Ions, New York, 1968.

  10. Morton, J.R. and Preston, K.K., J. Magn. Res., 1978, vol. 30, no.4, p. 577.

    CAS  Google Scholar 

  11. Murav’ev, V.I., Ovchinnikov, I.V., and Yunusov, N.B., Koord. Khim., 1978, vol. 4, no.6, p. 899.

    CAS  Google Scholar 

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  1. Research and Production Enterprise “Izmeritel’”, Ulyanovsk, Russia

    V. I. Murav’ev

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  1. V. I. Murav’ev
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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 6, 2005, pp. 423–426.

Original Russian Text Copyright © 2005 by Murav’ev.

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Murav’ev, V.I. To Interpretation of the EPR Parameters of Nitrosyl Complexes of Transition Metal Ions. Russ J Coord Chem 31, 398–400 (2005). https://doi.org/10.1007/s11173-005-0110-6

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  • DOI: https://doi.org/10.1007/s11173-005-0110-6

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