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Chiral coordination polymers based on Re cluster complexes, Cu2+ cations, and 1,2S,3S,4-tetraaminobutane

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Abstract

Reactions of octahedral and tetrahedral chalcocyanide cluster complexes of Re with Cu2+ cations and 1,2S,3S,4-tetraaminobutane (Threo-tab) were used to synthesize and study the structures of the following six novel chiral complexes: [{Cu2(NH3)(Threo-tab)3}Re6S8(CN)6] ⋅ 3H2O (I) (where Threo is 1,2S,3S,4-tetraaminobutane), [{Cu2(NH3)(Threo-tab)3}Re6Se8(CN)6] ⋅ 2H2O (II), [{Cu(Threo-tab)}2Re6Te8(CN)6] ⋅ 13.5H2O (III), [{Cu(Threo-tab)}2Re4Te4(CN)12] ⋅ 6.5H2O (IV), [{Cu2(NH3)(Threo-tab)2}Re4Te4(CN)12] ⋅ 4H2O (V), and [{Cu(NH3)(Threo-tab)}]2[Re4S3.4Te0.6(CN)12] ⋅ 1.25H2O (VI). The structures of complexes I–IV contain extended channels of sufficiently large size capable of including “guest” molecules.

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REFERENCES

  1. Hagrman, P.J., Hagrman, D., and Zubieta, J., Angew. Chem., Int. Ed. Engl., 1999, vol. 38, no.18, p. 2638.

    Google Scholar 

  2. Moulton, B. and Zaworotko, M.J., Chem. Rev., 2001, vol. 101, no.6, p. 1629.

    Article  CAS  PubMed  Google Scholar 

  3. Saalfrank, R.W., Uller, E., Demleitner, B., et al., Molecular Self Assembly, 2000, vol. 96, p. 149.

    CAS  Google Scholar 

  4. Eddaoudi, M., Moler, D.B., Li, H.L., et al., Account. Chem. Res., 2001, vol. 34, no.4, p. 319.

    Article  CAS  Google Scholar 

  5. Schubert, U.S. and Eschbaumer, C., Angew. Chem., Int. Ed. Engl., 2002, vol. 41, no.16, p. 2892.

    Google Scholar 

  6. Kitaura, R., Fujimoto, K., Noro, S., et al., Angew. Chem., Int. Ed. Engl., 2002, vol. 41, no.1, p. 133.

    Google Scholar 

  7. Tian, Y.Q., Cai, C.X., Ji, Y., et al., Angew. Chem., Int. Ed. Engl., 2002, vol. 41, no.8, p. 1384.

    Google Scholar 

  8. Park, K.M., Kim, S.Y., Heo, J., et al., J. Am. Chem. Soc., 2002, vol. 124, no.10, p. 2140.

    CAS  PubMed  Google Scholar 

  9. Xiong, R.G., Xue, X., Zhao, H., et al., Angew. Chem., Int. Ed. Engl., 2002, vol. 41, no.20, p. 3800.

    Google Scholar 

  10. Seeber, G., Pickering, A.L., Long, D.L., et al., J. Chem. Soc., Chem. Commun., 2003, no. 16, p. 2002.

  11. Pschirer, N.G., Ciurtin, D.M., Smith, M.D., et al., Angew. Chem., Int. Ed. Engl., 2002, vol. 41, no.4, p. 583.

    Google Scholar 

  12. Cui, Y., Evans, O.R., Ngo, H.L., et al., Angew. Chem., Int. Ed. Engl., 2002, vol. 41, no.7, p. 1159.

    Google Scholar 

  13. Mamula, O., Monlien, F.J., Porquet, A., et al., Chem. Eur. J., 2001, vol. 7, no.2, p. 533.

    CAS  Google Scholar 

  14. Plasseraud, L., Maid, H., Hampel, F., et al., Chem. Eur. J., 2001, vol. 7, no.18, p. 4007.

    CAS  Google Scholar 

  15. Zimmer, A., Kuppert, D., Weyhermuller, T., et al., Chem. Eur. J., 2001, vol. 7, no.4, p. 917.

    CAS  Google Scholar 

  16. Naumov, N.G., Virovets, A.V., Sokolov, M.N., et al., Angew. Chem., Int. Ed. Engl., 1998, vol. 37, nos.13–14, p. 1943.

    Google Scholar 

  17. Naumov, N.G., Virovets, A.V., and Fedorov, V.E., Inorg. Chem. Commun., 2000, vol. 3, no.2, p. 71.

    CAS  Google Scholar 

  18. Naumov, N.G., Soldatov, D.V., Ripmeester, J.A., et al., J. Chem. Soc., Chem. Commun., 2001, no. 6, p. 571.

  19. Mironov, Y.V., Oeckler, O., Simon, A., et al., Eur. J. Inorg. Chem., 2001, no. 11, p. 2751.

  20. Mironov, Y.V., Virovets, A.V., Sheldrick, W.S., et al., Polyhedron, 2001, vol. 20, nos.9–10, p. 969.

    Google Scholar 

  21. Mironov, Yu.V. and Fedorov, V.E., Izv. Ross. Akad. Nauk, Ser. Khim., 2002, no. 4, p. 529.

  22. Fedorov, V.E., Naumov, N.G., Mironov, Yu.V., et al, Zh. Strukt. Khim., 2002, vol. 43, no.4, p. 721.

    Google Scholar 

  23. Brylev, K.A., Mironov, Y.V., Naumov, N.G., et al., Inorg. Chem., 2004, vol. 43, no.16, p. 4833.

    CAS  PubMed  Google Scholar 

  24. Mironov, Y.V., Naumov, N.G., Brylev, K.A., et al., Angew. Chem., Int. Ed. Engl., 2004, vol. 43, no.10, p. 1297.

    Google Scholar 

  25. Mironov, Yu.V., Virovets, A.V., Artemkina, S.B., et al., Zh. Strukt. Khim., 1999, vol. 40, no.2, p. 375.

    Google Scholar 

  26. Slougui, A., Mironov, Y.V., Perrin, A., et al., Croat. Chem. Acta, 1995, vol. 68, no.4, p. 885.

    CAS  Google Scholar 

  27. Naumov, N.G., Virovets, A.V., Podberezskaya, N.V., et al, Zh. Strukt. Khim., 1997, vol. 38, no.5, p. 1018.

    Google Scholar 

  28. Imoto, Kh., Naumov, N.G., Virovets, A.V., et al., Zh. Strukt. Khim., 1998, vol. 39, no.5, p. 885.

    Google Scholar 

  29. Zimmer, A., Muller, I., Reiss, G.J., et al., Eur. J. Inorg. Chem., 1998, no. 12, p. 2079.

  30. Mironov, Y.V., Albrecht-Schmitt, T.E., and Ibers J.A., Inorg. Chem., 1997, vol. 36, no.5, p. 944.

    CAS  Google Scholar 

  31. Katayama, C., Acta Crystallogr., Sect. A: Found. Crystallogr., 1986, vol. 42, no.6, p. 19.

    Google Scholar 

  32. De Meulenaar, J. and Tompa, H., Acta Crystallogr., Sect. A, 1965, vol. 19, p. 1014.

    Google Scholar 

  33. Sheldrick, G.M., SHELXTL DOS/Windows/NT Version 6.14, Bruker Analytical X-Ray Instruments Inc., Madison (WI, USA), 2003.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. V. Mironov & K. A. Brylev

  2. Novosibirsk State University, Novosibirsk, Russia

    N. G. Naumov, O. A. Efremova & V. E. Fedorov

  3. Universitaet des Saarlandes Anorganische Chemie, Saarbruecken, Germany

    K. Hegetschweiler

Authors
  1. Yu. V. Mironov
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  2. N. G. Naumov
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  3. K. A. Brylev
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  4. O. A. Efremova
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  5. V. E. Fedorov
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  6. K. Hegetschweiler
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__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 4, 2005, pp. 289–301.

Original Russian Text Copyright © 2005 by Mironov, Naumov, Brylev, Efremova, Fedorov, Hegetschweiler.

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Mironov, Y.V., Naumov, N.G., Brylev, K.A. et al. Chiral coordination polymers based on Re cluster complexes, Cu2+ cations, and 1,2S,3S,4-tetraaminobutane. Russ J Coord Chem 31, 269–281 (2005). https://doi.org/10.1007/s11173-005-0088-0

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  • DOI: https://doi.org/10.1007/s11173-005-0088-0

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