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X-ray diffraction study of acid anilinium dodecatungstenphosphate

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Abstract

Acid anilinium dodecatungstenphosphate of composition (C6H5NH3)2H[PW12O40] ⋅ 2H2O is synthesized and characterized by X-ray diffraction analysis, IR spectroscopy, and thermogravimetry. The crystals are monoclinic: space group P21/m, a = 9.940(2) Å, b = 15.412(3) Å, c = 16.201(3) Å, β = 100.42(3)°, Z = 2, ρcalcd = 4.221 g/cm3. The structure contains heteropolyanions [PW12O40]3−, cations [C6H5NH3]+ and H+, and molecules of water of crystallization. The heteropolyanions and anilinium cations in crystal are linked by the electrostatic interaction and hydrogen bonds.

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Authors and Affiliations

  1. Moscow Pedagogical State University, Moscow, Russia

    G. Z. Kaziev, A. A. Dutov, A. M. Koroteev & N. V. Kuznetsova

  2. Universidad Antoroma Metropolitan Azcopotzalco, Mexico

    S. H. Quinones

  3. Karpov Research Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 103064, Russia

    V. K. Bel’skii & A. I. Stash

Authors
  1. G. Z. Kaziev
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  2. A. A. Dutov
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  3. S. H. Quinones
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  4. A. M. Koroteev
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  5. V. K. Bel’skii
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  6. A. I. Stash
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  7. N. V. Kuznetsova
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__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 4, 2005, pp. 273–279.

Original Russian Text Copyright © 2005 by Kaziev, Dutov, Quinones, Koroteev, Bel’skii, Stash, Kuznetsova.

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Kaziev, G.Z., Dutov, A.A., Quinones, S.H. et al. X-ray diffraction study of acid anilinium dodecatungstenphosphate. Russ J Coord Chem 31, 253–259 (2005). https://doi.org/10.1007/s11173-005-0086-2

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  • DOI: https://doi.org/10.1007/s11173-005-0086-2

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