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Crystal structure of monohydrate and anhydrous β-alaninium tetrafluoroantimonates(III)

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Abstract

Novel complexes of Sb(III) fluorides with cation of β-aminopropionic acid (β-alanine), (NH3(CH2)2COOH)SbF4 ⋅ H2O (I) and (NH3(CH2)2COOH)SbF4 (II), are synthesized and their crystal structures are determined. Crystals I and II are monoclinic with a = 12.1580(5) Å, b = 7.4167(4) Å, c = 10.1540(5) Å, β = 108.222(2)°, Z = 4, space group P21/c for (I) and a = 10.483(1) Å, b = 7.5906(8) Å, c = 9.4237(9) Å, β = 90.548(2)°, Z = 4, space group P21/c for (II). Structures I and II are formed by β-alaninium cations (C3H8NO2)+ and complex anions [SbF4] n−n with polymer chain structure. Complex I also contains crystallization water molecules. In the structures of complexes I and II, the β-alaninium cations have different conformation, the torsion angles C(1)C(2)C(3)N in these complexes are 174.5° and 77.0°C, respectively.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    A. A. Udovenko, L. A. Zemnukhova, E. V. Kovaleva & R. L. Davidovich

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  1. A. A. Udovenko
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  2. L. A. Zemnukhova
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  3. E. V. Kovaleva
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  4. R. L. Davidovich
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__________

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 4, 2005, pp. 243–247.

Original Russian Text Copyright © 2005 by Udovenko, Zemnukhova, Kovaleva, Davidovich.

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Udovenko, A.A., Zemnukhova, L.A., Kovaleva, E.V. et al. Crystal structure of monohydrate and anhydrous β-alaninium tetrafluoroantimonates(III). Russ J Coord Chem 31, 225–229 (2005). https://doi.org/10.1007/s11173-005-0081-7

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  • DOI: https://doi.org/10.1007/s11173-005-0081-7

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