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Thermochemistry of complex formation of Ni2+ with glycyl-L-asparagine in aqueous solutions

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Abstract

The heats of formation of complexes in the glycyl-L-asparagine—Ni2+ system were determined by calorimetry in an aqueous solution at ionic strengths of 0.5, 1.0, and 1.5 (KNO3) and a temperature of 298.15 K. The thermodynamic characteristics of the formation of nickel complexes with dipeptide were determined. The influence of the ligand structure on the complexation thermodynamics in solutions was discussed.

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REFERENCES

  1. Sigel, H., Metal Ions in Biological Systems, New York: Marsel Dekker, 1979, vol. 9.

    Google Scholar 

  2. Ismailov, D.I., Borisova, A.P., Savich, I.A., and Spitsin, V.I., Dokl. Akad. Nauk SSSR, 1972, vol. 207, no. 3, p. 651.

    Google Scholar 

  3. Korostelev, P.P., Prigotovlenie rastvorov dlya khimikoanaliticheskikh rabot (Preparation of Solutions for Analytical Chemistry), Moscow: Akad. Nauk SSSR, 1962.

    Google Scholar 

  4. Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemicals), Moscow: Khimiya, 1974.

    Google Scholar 

  5. Zelenin, O.Yu., Kochergina, L.A., and Vasil’ev, V.P., Zh. Fiz. Khim., 2004, vol. 78, no. 7, p. 1253.

    Google Scholar 

  6. Borodin, V.A., Vasil’ev, V.P., and Kozlovskii, E.V., Matematicheskie zadachi khimicheskoi termodinamiki (Mathematical Problems of Chemical Thermodynamics), Novosibirsk: Nauka, 1985, p. 219.

    Google Scholar 

  7. Vasil’ev, V.P., Kochergina, L.A., Gorboletova, G.G., and Popova, O.N., Zh. Fiz. Khim., 1999, vol. 73, no. 4, p. 677.

    Google Scholar 

  8. Nazorenko, V.A., Antonovich, V.P., and Nevskii, E.M., Gidroliz ionov metallov v razbavlennykh rastvorakh (Hydrolysis of Metal Ions in Dilute Solutions), Moscow: Atomizdat, 1979.

    Google Scholar 

  9. Vasil’ev, V.P. and Yasinskii, F.N., Zh. Neorg. Khim., 1978, vol. 23, no. 3, p. 579.

    Google Scholar 

  10. Vasil’ev, V.P., Kuturov, M.V., Kochergina, L.A., et al., Zh. Neorg. Khim., 1986, vol. 31, no. 6, p. 1479.

    Google Scholar 

  11. Zelenin, O.Yu., Kochergina, L.A., and Ratnikov, S.V., Koord. Khim., 2003, vol. 29, no. 7, p. 513.

    Google Scholar 

  12. Vasil’ev, V.P., Kochergina, L.A, and Kuturov, M.V., Zh. Neorg. Khim., 1983, vol. 28, no. 1, p. 141.

    Google Scholar 

  13. Kuturov, M.V. and Vasil’ev, V.P., Zh. Neorg. Khim., 1987, vol. 32, no. 10, p. 2479.

    Google Scholar 

  14. Vasil’ev, V.P., Vasil’eva, V.N., Dmitrieva, N.G., and Kokurin, N.I., Zh. Neorg. Khim., 1984, vol. 29, no. 5, p. 1123.

    Google Scholar 

  15. Vasil’ev, V.P., Dmitrieva, N.G., Vasil’eva, V.N, et al., Zh. Neorg. Khim., 1986, vol. 31, no. 12, p. 3044.

    Google Scholar 

  16. Termicheskie konstanty veshchestv (Thermal Constants of Substances), Glushko, V.P., Ed., Moscow, vols. 1–10, 1965–1983.

  17. Vasil’ev, V.P., Volkov, A.V., Gorboletova, G.G., and Kochergina, L.A., Zh. Fiz. Khim., 2001, vol. 75, no. 4, p. 590.

    Google Scholar 

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Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 2, 2005, pp. 143–148.

Original Russian Text Copyright © 2005 by Zelenin, Kochergina.

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Zelenin, O.Y., Kochergina, L.A. Thermochemistry of complex formation of Ni2+ with glycyl-L-asparagine in aqueous solutions. Russ J Coord Chem 31, 132–137 (2005). https://doi.org/10.1007/s11173-005-0048-8

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  • DOI: https://doi.org/10.1007/s11173-005-0048-8

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