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ESR and solid-state natural abundance 13C CP/MAS NMR study of crystalline alkyl (R = C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11) xanthate copper(II) and thallium(I) complexes

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Abstract

Crystalline thallium(I) alkylxanthate complexes [Tl{S(S)COR}] n (R = C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11) and isotope-substituted heteropolynuclear Cu(II)Tl(I) complexes [63(65)CuTl6(S2COR)8] (R= i-C4H9 and C5H11) were obtained and studied by ESR and high-resolution solid-state 13C CP/MAS NMR spectroscopy. According to the 13C NMR data, polynuclear thallium(I) complexes contain structurally equivalent alkylxanthate ligands. The ESR study revealed the Jahn-Teller dynamic effect in Cu(II)Tl(I) complexes; the nuclei of six Tl atoms are involved in the hyperfine interaction.

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Authors and Affiliations

  1. Amur Institute of Integrated Research, Far East Division, Russian Academy of Sciences, Relochnyi per. 1, 675000, Blagoveshchensk, Russia

    A. V. Ivanov

  2. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    O. A. Bredyuk

  3. Luleå University of Technology, S-971 87, Luleå, Sweden

    O. N. Antzutkin & W. Forsling

Authors
  1. A. V. Ivanov
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  2. O. A. Bredyuk
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  3. O. N. Antzutkin
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  4. W. Forsling
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Additional information

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 1, 2005, pp. 48–54.

Original Russian Text Copyright © 2005 by Ivanov, Bredyuk, Antzutkin, Forsling.

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Ivanov, A.V., Bredyuk, O.A., Antzutkin, O.N. et al. ESR and solid-state natural abundance 13C CP/MAS NMR study of crystalline alkyl (R = C2H5, i-C3H7, i-C4H9, s-C4H9, and C5H11) xanthate copper(II) and thallium(I) complexes. Russ J Coord Chem 31, 45–50 (2005). https://doi.org/10.1007/s11173-005-0047-9

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  • DOI: https://doi.org/10.1007/s11173-005-0047-9

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