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Tetranuclear bismuth complexes Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2C6H6 and Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2C6H4Me2-1,4: Synthesis and structures

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Abstract

X-ray diffraction study of tetranuclear organobismuth complexes Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2η6-C6H6 and Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2(C6H4Me2-1,4) revealed four Bi atoms connected through the bridging carboxylate ligands and the O atoms. The coordination sphere of the terminal Bi atoms includes the chelate carboxylate ligand and the η6-arene molecule. The bridging O atoms are tricoordinated, the distances between the terminal Bi atom and the center of benzene molecule (1,4-dimethylbenzene) are 3.024 Å(3.131 Å).

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REFERENCES

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, ul. Lenina 104, 675000, Blagoveshchensk, Russia

    V. V. Sharutin, I. V. Egorova, O. K. Sharutina & T. K. Ivanenko

  2. Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    N. Yu. Adonin & V. F. Starichenko

  3. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 109, 690022, Vladivostok, Russia

    M. A. Pushilin & A. V. Gerasimenko

Authors
  1. V. V. Sharutin
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  2. I. V. Egorova
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  3. O. K. Sharutina
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  4. T. K. Ivanenko
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  5. N. Yu. Adonin
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  6. V. F. Starichenko
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  7. M. A. Pushilin
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  8. A. V. Gerasimenko
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Additional information

Translated from Koordinatsionnaya Khimiya, Vol. 31, No. 1, 2005, pp. 4–11.

Original Russian Text Copyright © 2005 by Sharutin, Egorova, Sharutina, Ivanenko, Adonin, Starichenko, Pushilin, Gerasimenko.

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Sharutin, V.V., Egorova, I.V., Sharutina, O.K. et al. Tetranuclear bismuth complexes Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2C6H6 and Bi4(O)2(O2CC6H2F3-3,4,5)8 · 2C6H4Me2-1,4: Synthesis and structures. Russ J Coord Chem 31, 2–8 (2005). https://doi.org/10.1007/s11173-005-0019-0

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  • DOI: https://doi.org/10.1007/s11173-005-0019-0

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