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Some properties of rhodium thioselenochloride RhCl4Se6S9 and its thermal conversion products

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Abstract

The structure of rhodium thioselenochloride RhCl4Se6S9 and the products of its thermal decomposition are studied by X-ray photoelectron and IR spectroscopies, X-ray powder diffraction, thermal, and elemental analyses. The thermal decomposition of RhCl4Se6S9 was found to occur with a loss of weakly bonded chloro-, sulfur-, and selenium-containing fragments (at 100°C); at the higher temperatures, chlorine is lost and rhodium thioselenides are obtained (Rh4Se4S5 at 490°C and Rh4Se3S5 at 665°C). These changes are attended by the formation of the cluster nucleus [Rh4(µ3-Se)3(µ3-S)].

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Authors and Affiliations

  1. Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, Ukraine

    V. I. Pekhno, I. N. Stepanenko, S. V. Volkov & Z. A. Fokina

  2. Institute of Metal Physics, National Academy of Sciences of Ukraine, pr. Vernadskogo, 36, Kiev, Ukraine

    A. M. Korduban

Authors
  1. V. I. Pekhno
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  2. I. N. Stepanenko
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  3. S. V. Volkov
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  4. Z. A. Fokina
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  5. A. M. Korduban
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Additional information

Translated from Koordinatsionnaya Khimiya, Vol. 30, No. 12, 2004, pp. 910–914.

Original Russian Text Copyright © 2004 by Pekhno, Stepanenko, Volkov, Fokina, Korduban.

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Pekhno, V.I., Stepanenko, I.N., Volkov, S.V. et al. Some properties of rhodium thioselenochloride RhCl4Se6S9 and its thermal conversion products. Russ J Coord Chem 30, 859–863 (2004). https://doi.org/10.1007/s11173-005-0005-6

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  • DOI: https://doi.org/10.1007/s11173-005-0005-6

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