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Efficient synthetic approach to 1-aza- and 1,2,4-triazatriptycenes

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Abstract

Convenient methods for the preparation of (het)aryl-substituted derivatives of 1-azatriptycene, including the cyclopentene-condensed analog, were proposed using the “1,2,4-triazine” methodology. The 1,2,4-triazatriptycene derivatives were synthesized for the first time. New original ligands of the 2,2′-bipyridine series are among the synthesized compounds.

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Funding

This work was financially supported by the Russian Science Foundation (Project No. 21-13-00304) and Council on Grants at the President of the Russian Federation (Project No. NSh-1223.2022.1.3).

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Correspondence to D. S. Kopchuk.

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No human or animal subjects were used in this research.

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The authors declare no competing interests.

Additional information

Based on the materials of the VII International Conference “Modern Synthetic Methodologies for Creating Drugs and Functional Materials” (MOSM 2023) dedicated to the 125th birth anniversary of Academician I. Ya. Postovsky (September 10–16, 2023, Yekaterinburg—Perm, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 12, pp. 3032–3036, December, 2023

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Rybakova, S.S., Valieva, M.I., Kudryashova, E.A. et al. Efficient synthetic approach to 1-aza- and 1,2,4-triazatriptycenes. Russ Chem Bull 72, 3032–3036 (2023). https://doi.org/10.1007/s11172-023-4115-4

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  • DOI: https://doi.org/10.1007/s11172-023-4115-4

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