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Phthalocyanine-catalyzed oxidation of phenol with ammonium persulfate

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Abstract

The oxidation of phenol with ammonium persulfate (NH4)2S2O8 carried out under conditions of the Elbs reaction and catalyzed by metal phthalocyanines was explored. The conditions were optimized for increasing the yield of hydroquinone up to 85% upon the 95% conversion of phenol. Phthalocyanines of FeII, FeIII, and Co were found to be the most active catalysts.

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Funding

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation (State Assignment No. 122031400278-2). Spectral experiments were carried out using the equipment of the Center for Collective Use “Chemistry” at the Ufa Institute of Chemistry at the Ufa Federal Research Centre of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Ufa Institute of Chemistry at Ufa Federal Research Center, Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054, Ufa, Russian Federation

    A. R. Gimadieva, Yu. Z. Khazimullina, I. B. Abdrakhmanov & A. G. Mustafin

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  1. A. R. Gimadieva
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  2. Yu. Z. Khazimullina
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  3. I. B. Abdrakhmanov
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  4. A. G. Mustafin
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Correspondence to A. R. Gimadieva.

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The authors declare no competing interests.

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Dedicated to the memory of Academician of the Russian Academy of Sciences G. A. Tolstikov (1933–2013).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 10, pp. 2372–2376, October, 2023.

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Gimadieva, A.R., Khazimullina, Y.Z., Abdrakhmanov, I.B. et al. Phthalocyanine-catalyzed oxidation of phenol with ammonium persulfate. Russ Chem Bull 72, 2372–2376 (2023). https://doi.org/10.1007/s11172-023-4035-3

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  • DOI: https://doi.org/10.1007/s11172-023-4035-3

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