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Crystalline and amorphous aluminosilicates with varying pore structures in the synthesis of 1,5-benzodiazepine

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Abstract

The catalytic properties of zeolites (microporous H-Y and granular micro-mesomacroporous H-Yh) and amorphous mesoporous aluminosilicate ASM in the reaction of 1,2-phenylenediamine with acetone were studied. The main reaction product was 2,2,4-trimethyl-2,3-dihydro-1H-1,5-benzodiazepine (selectivity up to 99% at a 94% conversion of 1,2-phenylenediamine). For the synthesis of 1,5-benzodiazepine, the most effective was 0.95H-Yh, a granular zeolite with a hierarchical porous structure. The catalyst demonstrated operational stability for three cycles.

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Funding

The work was performed in the framework of the state assignment of the Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences (Topic No. FMRS-2022-0080). Structural studies were carried out at the Agidel Regional Center for Collective Use of the Ufa Federal Research Center of the Russian Academy of Sciences within the framework of the state assignment of the Institute of Petrochemistry and Catalysis of the Ufa Federal Research Center of the Russian Academy of Sciences (Topic No. FMRS-2022-0081).

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    N. G. Grigorieva, S. V. Bubennov, N. A. Filippova, A. S. Artem’eva, V. R. Bikbaeva & B. I. Kutepov

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  1. N. G. Grigorieva
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  2. S. V. Bubennov
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  3. N. A. Filippova
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  4. A. S. Artem’eva
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  5. V. R. Bikbaeva
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  6. B. I. Kutepov
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Correspondence to N. G. Grigorieva.

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Dedicated to the memory of Academician of the Russian Academy of Sciences G. A. Tolstikov (1933–2013).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 10, pp. 2357–2365, October, 2023.

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Grigorieva, N.G., Bubennov, S.V., Filippova, N.A. et al. Crystalline and amorphous aluminosilicates with varying pore structures in the synthesis of 1,5-benzodiazepine. Russ Chem Bull 72, 2357–2365 (2023). https://doi.org/10.1007/s11172-023-4033-5

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  • DOI: https://doi.org/10.1007/s11172-023-4033-5

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