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Phase equilibria and extraction of metal ions in systems based on mixtures of oxyethylated nonylphenols

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Abstract

According to the study of phase equilibria in a neonol AF 9–10—neonol AF 9–12—water system made by the visual polythermal method, the immiscibility area in the system exists at temperatures above 68 °C and its formation is associated with a limited solubility of the surfactant in water at the temperatures studied. The conditions for the quantitative extraction of thallium(iii) in the form of bromide and thiocanate complexes and iron(iii) in the form of thiocyanate complexes in the neonol AF 9–10—water system at 85 °C were established. The use of a mixture of neonols in the absence of a salting agent gives no special advantages over the use of the neonol AF 9–10—water system.

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Authors and Affiliations

  1. Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Perm Federal Research Center of the Ural Branch of the Russian Academy of Sciences, 3 ul. Akademika Koroleva, 614013, Perm, Russian Federation

    D. O. Shilykovskaya

  2. Perm State National Research University, 15 ul. Bukireva, 614990, Perm, Russian Federation

    D. O. Shilykovskaya, A. M. Elokhov & S. A. Denisova

  3. Perm State Agrarian and Technological University, 23 ul. Petropavlovskaya, 614990, Perm, Russian Federation

    A. E. Lesnov

Authors
  1. D. O. Shilykovskaya
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  2. A. M. Elokhov
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  3. S. A. Denisova
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  4. A. E. Lesnov
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Corresponding author

Correspondence to A. M. Elokhov.

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The authors declare no competing interests.

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No human or animal subjects were used in this research.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 9, pp. 2036–2040, September, 2023.

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Shilykovskaya, D.O., Elokhov, A.M., Denisova, S.A. et al. Phase equilibria and extraction of metal ions in systems based on mixtures of oxyethylated nonylphenols. Russ Chem Bull 72, 2036–2040 (2023). https://doi.org/10.1007/s11172-023-3997-5

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  • DOI: https://doi.org/10.1007/s11172-023-3997-5

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