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Synthesis of active carbon from nutshell Macadamia and its adsorption affinity toward methane

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Russian Chemical Bulletin Aims and scope

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Abstract

The microporous carbon adsorbent with the specific micropore volume W0 = 0.80 cm3 g−1, micropore width X0 = 1.32 nm, and specific surface area SBET = 2115 m2 g−1 was synthesized by the thermochemical activation method from the carbonizate of nutshell Macadamia in the presence of orthophosphoric acid at 1173 K. At 303 K and 20 MPa, the adsorption capacity of the adsorbent to methane reaches ∼22 wt.%. The volume density of adsorbed methane on the compacted carbon adsorbent with the binder at a pressure of 10 MPa was found to be ~200 nm3 m−3.*

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Correspondence to Nguyen Dinh Tuyen or A. A. Pribylov.

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The authors declare no competing interests.

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This work was carried out within the framework of the state assignment of the Ministry of Science and Higher Education of the Russian Federation (theme No. 122011300053-8) with financial support of the Institute of Environmental Technology of the Vietnam Academy of Science and Technology (Grant No. CSCL.01/22-23) in accord with the plan of the Scientific Council on Physical Chemistry of the Russian Academy of Sciences (theme No. 23-03-460-01).

No human or animal subjects were used in this research.

The amount of methane (m3) in 1 m3 of the storage system at a normal temperature of 293 K and a pressure of 101 kPa is indicated.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 9, pp. 2025–2030, September, 2023.

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Tuyen, N.D., Pribylov, A.A., Fomkin, A.A. et al. Synthesis of active carbon from nutshell Macadamia and its adsorption affinity toward methane. Russ Chem Bull 72, 2025–2030 (2023). https://doi.org/10.1007/s11172-023-3995-7

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  • DOI: https://doi.org/10.1007/s11172-023-3995-7

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