Abstract
Thermodynamic instability of the trivalent phosphorus embedded in a carbon plane was estimated experimentally and theoretically. The change in the electronic state of phosphorus upon exposure of the sample to air was demonstrated using XPS and solid state NMR methods.
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This work was financially supported by the Russian Science Foundation (Project No. 19-73-20124).
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Published in Russian in Izvestiya AkademiiNauk. Seriya Khimicheskaya, Vol. 72, No. 9, pp. 2006–2012, September, 2023.
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Galushko, A.S., Shaydullin, R.R., Kulikovskaya, N.S. et al. Theoretical and experimental investigations of the PIII/PV transition in a phosphorus-doped carbon material. Russ Chem Bull 72, 2006–2012 (2023). https://doi.org/10.1007/s11172-023-3993-9
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DOI: https://doi.org/10.1007/s11172-023-3993-9