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1,1,3,3-Tetramethylguanidine-iodine system as an efficient catalyst for CO2 addition to oxiranes

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Abstract

A catalytic system obtained by mixing 1,1,3,3-tetramethylguanidine and iodine was tested for the reaction of monosubstituted oxiranes with CO2 affording organic cyclic carbonates. The catalyst turned out to be effective not only for substrates with substituents, which have different sizes and donor-acceptor properties, but also in the case of bis-oxiranes.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov & P. V. Cherkasova

Authors
  1. S. E. Lyubimov
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  2. P. V. Cherkasova
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Corresponding author

Correspondence to S. E. Lyubimov.

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The authors declare no competing interests.

Additional information

The work was carried out within the framework of the State Assignment of the Ministry of Science and Higher Education of the Russian Federation (No. 075-03-2023-642).

No human or animal subjects were used in this research.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 72, No. 8, pp. 1933–1935, August, 2023.

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Lyubimov, S.E., Cherkasova, P.V. 1,1,3,3-Tetramethylguanidine-iodine system as an efficient catalyst for CO2 addition to oxiranes. Russ Chem Bull 72, 1933–1935 (2023). https://doi.org/10.1007/s11172-023-3979-7

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  • DOI: https://doi.org/10.1007/s11172-023-3979-7

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